Volume 107; Issue 9

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Journal of the American Chemical Society
Volume 107; Issue 9

Journal of the American Chemical Society

Volume 107; Issue 9

1

Azide and fluoride exchange reactions of halodiazirines

Moss, Robert A., Terpinski, Jacek, Cox, D. Phillip, Denny, Dorothy Z., Krogh-Jespersen, Karsten

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 821 KB

english, 1985

2

Assignment of complex proton NMR spectra via two-dimensional homonuclear Hartmann-Hahn spectroscopy

Davis, Donald G., Bax, Ad

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 256 KB

english, 1985

3

Topochemical double photocyclodimerization of the 1,4-dicinnamoylbenzene crystal

Hasegawa, Masaki, Saigo, Kazuhiko, Mori, Toru, Uno, Hirofumi, Nohara, Masao, Nakanishi, Hachiro

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 696 KB

english, 1985

4

The octant rule. 13. Axial and equatorial 4-tert-butyladamantan-2-ones. Synthesis, circular dichroism, and mass spectra

Lightner, David A., Wijekoon, W. M. Donald

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 412 KB

english, 1985

5

A heteropolyanion with fivefold molecular symmetry that contains a nonlabile encapsulated sodium ion. The structure and chemistry of [NaP5W30O110]14-

Alizadeh, Mohammed H., Harmalker, Subhash P., Jeannin, Yves, Martin-Frere, Jeanne, Pope, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.01 MB

english, 1985

6

The intrinsic reaction coordinate and the rotational barrier in silaethylene

Schmidt, Michael W., Gordon, Mark S., Dupuis, Michel

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 706 KB

english, 1985

7

Kinetics of ozonation. 3. Substituent effects on the rates of reaction of alkenes

Pryor, William A., Giamalva, David, Church, Daniel F.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 629 KB

english, 1985

8

Theoretical study on the dimerization of silanone and the properties of the polymeric products (H2SiO)n (n = 2, 3, and 4). Comparison with dimers (H2SiS)2 and (H2CO)2

Kudo, Takako, Nagase, Shigeru

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 809 KB

english, 1985

9

Nitrogen-14 and nitrogen-15 ENDOR studies of intrabridgehead three-electron .sigma.-bonded radical cations. Observation of second-order splittings

Kirste, B., Alder, R. W., Sessions, R. B., Bock, M., Kurreck, H., Nelsen, S. F.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 682 KB

english, 1985

10

Bridgehead adamantyl, diamantyl, and related cations and dications

Olah, George A., Prakash, G. K. Surya, Shih, Joseph G., Krishnamurthy, V. V., Mateescu, Gheorge D., Liang, Gao, Sipos, Gyorgy, Buss, Volker, Gund, Tamara M., Schleyer, Paul v. R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 2.01 MB

english, 1985

11

Cobalt-59 NMR chemical shifts of cobalt(III) complexes; correlations with parameters calculated from ligand-field spectra

Bramley, Richard, Brorson, Michael, Sargeson, Alan M., Schaeffer, Claus E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.12 MB

english, 1985

12

Kinetic isotope effect in gas-phase base-induced elimination reactions

Bierbaum, Veronica M., Filley, Jonathan, DePuy, Charles H., Jarrold, Martin F., Bowers, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 412 KB

english, 1985

13

A new method for obtaining isotopic fractionation data at multiple sites in rapidly exchanging systems

Jarret, Ronald M., Saunders, Martin

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 948 KB

english, 1985

14

A study of L-proline, sarcosine, and the cis/trans isomers of N-acetyl-L-proline and N-acetylsarcosine in aqueous and organic solution by oxygen-17 NMR

Hunston, Roger N., Gerothanassis, Ioannis P., Lauterwein, Juergen

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1004 KB

english, 1985

15

High-speed spatially resolved high-resolution NMR spectroscopy

Matsui, Shigeru, Sekihara, Kensuke, Kohno, Hideki

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 264 KB

english, 1985

16

Stereoselective total synthesis of the complement inhibitor K-76

McMurry, John E., Erion, Mark D.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.21 MB

english, 1985

17

Acyclic diastereoselection as a synthetic route to quassinoids: a Claisen rearrangement based strategy for bruceantin

Ziegler, Frederick E., Klein, Scott I., Pati, Uttam K., Wang, Tein Fu

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.06 MB

english, 1985

18

Laser flash photolysis study of the photochemistry of ring-substituted .beta.-phenylpropiophenones

Netto-Ferreira, J. C., Leigh, W. J., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 783 KB

english, 1985

19

Multiple substitutions in radical-chain chlorinations. A new cage effect

Skell, Phillip S., Baxter, H. N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 285 KB

english, 1985

20

Bridging the gap. A continuous scale of gas-phase basicities from methane to water from pulsed electron beam high pressure mass spectrometric equilibria measurements

McMahon, T. B., Kebarle, P.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 762 KB

english, 1985

21

Are carbenium ions stabilized or destabilized by .alpha.-silyl substitution? The solvolysis of 2-(trimethylsilyl)-2-adamantyl p-nitrobenzoate

Apeloig, Yitzhak, Stanger, Amnon

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 287 KB

english, 1985

22

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 846 KB

english, 1985

23

Relative importance of dissociative loss of carbon monoxide and formation of benzyl radicals from photoexcitation of (.eta.5-C5R5)Fe(CO)2(.eta.1-CH2C6H5) and evidence for reaction of carbon monoxide with 17-electron radicals

Blaha, Josephine Paw, Wrighton, Mark S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.12 MB

english, 1985

24

Masthead

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 142 KB

english, 1985

25

Nucleophilic displacement vs. proton transfer: the system hydrated hydroxide ion + chloromethane [OH-.cntdot.(H2O)0,1,2 + CH3Cl] in the relative energy range 0.03-5 eV

Henchman, Michael, Hierl, Peter M., Paulson, John F.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 392 KB

english, 1985

26

Detection of hydrogen, hydrogen-deuterium molecule (HD), and deuterium by Raman spectroscopy: a powerful aid for the elucidation of reaction mechanisms

Best, Stephen P., Bloodworth, A. J., Clark, Robin J. H., Eggelte, Henny J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 382 KB

english, 1985

27

Mechanism of adenylate kinase. 1. Use of oxygen-17 NMR to study the binding properties of substrates

Wisner, Daniel A., Steginsky, Corazon A., Shyy, Yeun Jund, Tsai, Ming Daw

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 269 KB

english, 1985

28

Mixed-valence manganese(II)-manganese(III) complexes: models for the manganese site in the photosynthetic electron transport chain

Mabad, Bouchra, Tuchagues, Jean Pierre, Hwang, Yeong Tsyr, Hendrickson, David N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 300 KB

english, 1985

29

Theoretical electron deformation density studies on chromium benzene tricarbonyl

Kok, Randall A., Hall, Michael B.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 721 KB

english, 1985

30

Molecular receptors. Synthesis, x-ray crystal structures, and chemical properties of crown ethers bearing an intraannular phenolic group

Browne, Christine M., Ferguson, George, McKervey, M. Anthony, Mulholland, D. Lindsay, O'Connor, Thomas, Parvez, Masood

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.20 MB

english, 1985

31

Magnetic properties of manganese in the photosynthetic oxygen-evolving complex

De Paula, Julio C., Brudvig, Gary W.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 710 KB

english, 1985

32

Dynamic transduction of energy and internal equilibria in enzymes: a reexamination of pyruvate kinase

Stackhouse, Joseph, Nambiar, Krishnan P., Burbaum, Jonathan J., Stauffer, Dora M., Benner, Steven A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 940 KB

english, 1985

33

Aqualigand dissociation of nonaaquacerium(3+) ion in the 5d .rarw. 4f excited state

Kaizu, Youkoh, Miyakawa, Koji, Okada, Keiko, Kobayashi, Hiroshi, Sumitani, Minoru, Yoshihara, Keitaro

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 570 KB

english, 1985

34

The role of lithium salts in controlling the regiochemistry of the alkylation of a lithium enolate in a weakly polar aprotic solvent

Jackman, L. M., Dunne, T. S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 302 KB

english, 1985

35

Remarkable structures of C2B2H4 isomers

Budzelaar, Peter H. M., Krogh-Jespersen, Karsten, Clark, Timothy, Schleyer, Paul v. R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 801 KB

english, 1985

36

Polysilane high polymers: mechanism of photodegradation

Trefonas, Peter, West, Robert, Miller, Robert D.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 815 KB

english, 1985

37

Fusogenic behavior of didodecyldimethylammonium bromide bilayer vesicles

Rupert, Leo A. M., Hoekstra, Dick, Engberts, Jan B. F. N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.41 MB

english, 1985

38

Stereocontrolled functionalization in the cyclohexane ring using organomolybdenum chemistry

Pearson, Anthony J., Khan, M. Nazrul I., Clardy, Jon C., He, Cun Heng

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.34 MB

english, 1985

39

Reactions of the metal carbenes FeCH2+ and CoCH2+ with olefins in the gas phase. Studies involving olefin metathesis

Jacobson, D. B., Freiser, B. S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 913 KB

english, 1985

40

Ab initio calculations on the diphosphine radical cation (P2H4+.cntdot.)

Feller, David, Davidson, Ernest R., Borden, Weston Thatcher

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 272 KB

english, 1985

41

Electrochemistry of polymer films not immersed in solution: electron transfer on an ion budget

Jernigan, Joseph C., Chidsey, Christopher E. D., Murray, Royce W.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 441 KB

english, 1985

42

Electron-rich, hydrocarbon-metal complexes: synthesis and reversible one-electron oxidation. X-ray structure of a 17-electron iron cation

Grosselin, Jean Michel, Le Bozec, Hubert, Moinet, Claude, Toupet, Loic, Dixneuf, Pierre H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 431 KB

english, 1985

43

Transition structures for additions of lithium hydride and methyllithium to ethylene and acetylene

Houk, Kendall N., Rondan, Nelson G., Schleyer, Paul v. R., Kaufmann, E., Clark, Timothy

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 349 KB

english, 1985

44

Kinetics of reduction of eight viologens by dithionite ion

Tsukahara, K., Wilkins, R. G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 508 KB

english, 1985

45

Surprising stereochemical control of Wittig olefination involving reaction of fluorine-containing phosphoranium salt and aldehydes

Cox, Daryl G., Gurusamy, Narayanasamy, Burton, Donald J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 275 KB

english, 1985

46

Conformation, configuration, and reactivity of thiosulfonium ions derived from 1,2-dithianes and 1,2-dithiolanes. Stereoelectronic effects

Caserio, Marjorie C., Kim, Jhong K., Kahn, Scott D., Hehre, Warren J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 426 KB

english, 1985

47

Ring transformation equilibrium (bond switch) in 5-(2-aminovinyl)isothiazole system via hypervalent sulfurane. Synthesis, structure determination, and kinetic study

Akiba, Kinya, Kashiwagi, Kohichi, Ohyama, Yoshihiko, Yamamoto, Yohsuke, Ohkata, Katsuo

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.20 MB

english, 1985

48

Anisotropy and asymmetry of the diamagnetic susceptibility of the carbonium ion of anthracene

Van Zijl, P. C. M., Kostermans, G. B. M., MacLean, C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 390 KB

english, 1985

49

Kinetics and mechanism of the insertion of olefins into transition metal-hydride bonds

Doherty, Nancy M., Bercaw, John E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.58 MB

english, 1985

50

The diphosphine radical cation (P2H4+.cntdot.)

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 387 KB

english, 1985

51

Geometrical isomers of a bridgehead imine: (E)- and (Z)-2-azabicyclo[3.2.1]oct-1-ene, and 2-azabicyclo[2.2.2]oct-1-ene

Radziszewski, Juliusz G., Downing, John W., Wentrup, Curt, Kaszynski, Piotr, Jawdosiuk, Mikolaj, Kovacic, Peter, Michl, Josef

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 420 KB

english, 1985

52

Photochemistry of ketones in solution. 74. Characterization of transient intermediates on laser flash excitation of cyclohexenones in the presence of amines

Dunn, D. A., Schuster, D. I., Bonneau, R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 411 KB

english, 1985

53

Ab initio MO study of the coordination modes and bonding nature of rhodium(I)-dinitrogen complexes

Sakaki, Shigeyoshi, Morokuma, Keiji, Ohkubo, Katsutoshi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.01 MB

english, 1985

54

Spectroscopic determination of .sigma.I and .sigma.R substituent constants for the deuterium atom

Kuenzer, H., Berger, S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 290 KB

english, 1985

55

Acyclic stereoselection. 29. Stereoselection in the Michael addition reaction. 1. The Mukaiyama-Michael reaction

Heathcock, Clayton H., Norman, Mark H., Uehling, David E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 360 KB

english, 1985

56

A molecular orbital evaluation of possible factors affecting the homolytic activation of coenzyme B12

Christianson, David W., Lipscomb, William N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 614 KB

english, 1985

57

Charge distribution in diatomic halides from electron spectroscopy

Saethre, Leif J., Thomas, T. Darrah, Gropen, Odd

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 608 KB

english, 1985