Volume 108; Issue 25

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Journal of the American Chemical Society
Volume 108; Issue 25

Journal of the American Chemical Society

Volume 108; Issue 25

1

Pyrophosphate formation for acetyl phosphate and orthophosphate anions in concentrated aqueous salt solutions does not provide evidence for a metaphosphate intermediate

Herschlag, Daniel., Jencks, William P.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.22 MB

english, 1986

2

Evaluation of AM1 calculated proton affinities and deprotonation enthalpies

Dewar, Michael J. S., Dieter, Kenneth M.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.35 MB

english, 1986

3

Benzoannelated centropolyquinanes. 2. (all-cis)-Tetrabenzotetracyclo[5.5.1.04,13.010,13]tridecane, "fenestrindan"

Kuck, Dietmar., Boegge, Hartmut.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 359 KB

english, 1986

4

Cross-sectional areas of alkanoic acids. A comparative study applying fractal theory of adsorption and considerations of molecular shape

Meyer, Amatzya Y., Farin, Dina., Avnir, David.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.17 MB

english, 1986

5

General transannulation approach to angular triquinanes. Total syntheses of (.+-.)-pentalenene and (.+-.)-epi-pentalenene

Mehta, Goverdhan., Rao, Kasibhatla Srinivas.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.06 MB

english, 1986

6

Infrared spectroscopic evidence for silicon-oxygen double bonds: methyl- and dimethylsilanones in solid argon

Withnall, Robert., Andrews, Lester.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 226 KB

english, 1986

7

General acid catalyzed acetal hydrolysis. The hydrolysis of acetals and ketals of cis- and trans-1,2-cyclohexanediol. Changes in rate-determining step and mechanism as a function of pH

Fife, Thomas H., Natarajan, R.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 920 KB

english, 1986

8

Fluorescent heterocyclic systems: syntheses, structures, and physicochemical properties of dipyrido-substituted 1,3,4,6-tetraazapentalenes

Groziak, Michael P., Wilson, Scott R., Clauson, Gary L., Leonard, Nelson J.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 645 KB

english, 1986

9

Synthesis and x-ray structure of the [HNi38(CO)42C6]5- cluster: an extended fragment of the Cr23C6 lattice stabilized in a molecular carbonyl nickel cluster

Ceriotti, Alessandro., Fait, Anna., Longoni, Giuliano., Piro, Giampietro., Demartin, Francesco., Manassero, Mario., Masciocchi, Norberto., Sansoni, Mirella.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 302 KB

english, 1986

10

Organometallic nitrosyl chemistry. 29. Proton NMR spectroscopic criteria for elucidating the structures of bimetallic organotungsten hydrides in solutions. Crystal and molecular structures of [CpW(NO)H]2(.mu.-H)2

Legzdins, Peter., Martin, Jeffrey T., Einstein, Frederick W. B., Willis, Anthony C.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.28 MB

english, 1986

11

Functionalized Keggin- and Dawson-type cyclopentadienyltitanium heteropolytungstate anions: small, individually distinguishable labels for conventional transmission electron microscopy. 2. Reactions

Keana, John F. W., Ogan, Marc D., Lu, Yixin., Beer, Michael., Varkey, J.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 2.15 MB

english, 1986

12

The kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 4. Catalysis by meso-[tetrakis(2,6-dimethylphenyl)porphinato]iron(III) chloride

Woon, T. C., Dicken, C. Michael., Bruice, Thomas C.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 779 KB

english, 1986

13

Synthesis of "iso-EPSP" and evaluation of its interaction with chorismate synthase

Bartlett, Paul A., Maitra, Uday., Chouinard, Paul M.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 597 KB

english, 1986

14

A correlation between .beta.-hydrogen isotope effects on carbon-13 NMR chemical shifts in unsaturated systems and the strength of hyperconjugative interactions

Arrowsmith, Cheryl H., Kresge, A. Jerry.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 400 KB

english, 1986

15

Correction. Dehydrogenation of Isobutane by Oxygen-Deficient Cobalt/Oxygen Cluster Ions

Freas, R B., Campana, J E.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 121 KB

english, 1986

16

Photodriven electron transfer in triad molecules: a two-step charge-recombination reaction

Gust, Devens., Moore, Thomas A., Makings, Lewis R., Liddell, Paul A., Nemeth, Gregory A., Moore, Ana L.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 502 KB

english, 1986

17

Theoretical evidence for two geometrical isomers of silver oxide (AgO2)

Illas, F., Rubio, J., Ricart, J. M., Cabot, P. L.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 695 KB

english, 1986

18

Correlation effects on semiempirical transition states

Schroeder, Stefan., Thiel, Walter.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 586 KB

english, 1986

19

How does a reaction change its mechanism? General base catalysis of the addition of alcohols to 1-phenylethyl carbocations

Ta-Shma, Rachel., Jencks, William P.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.34 MB

english, 1986

20

Quantitation of deuterium-hydrogen NMR isotope effects on carbon-13 chemical shifts. Linear correlations associated with hybridization and charge density changes in norbornenyl systems

Kuenzer, Hermann., Cottrell, Charles E., Paquette, Leo A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 431 KB

english, 1986

21

Theoretical studies of the reactions XHn .fwdarw. XHn-1- + H+ and XHn-1- + SiH4 .fwdarw. [SiH4XHn-1]-

Gordon, Mark S., Davis, Larry P., Burggraf, Larry W., Damrauer, Robert.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 644 KB

english, 1986

22

Torands: rigid toroidal macrocycles. Calcium sequestration by a member of this new ligand class

Bell, Thomas W., Firestone, Albert.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 404 KB

english, 1986

23

Electrophilic capture by conjugated bis(bicyclo[1.1.0]butanes). Site specificity of the initiation step and thermodynamic control of the ensuing electronic reorganization

Paquette, L. A., Lau, C. J., Browne, A. R., O'Brien, M. E.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 272 KB

english, 1986

24

Computer Software Reviews

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 334 KB

english, 1986

25

Photoreduction of carbon dioxide to methane in aqueous solutions using visible light

Maidan, Ruben., Willner, Itamar.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 297 KB

english, 1986

26

Chirality transmission via a 6-endo free-radical-mediated cyclization process: regio- and stereocontrolled synthesis of the 22-hydroxylated steroid side chains

Koreeda, Masato., George, Irene A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 428 KB

english, 1986

27

Oxygenated cytochrome P-450-CAM and chloroperoxidase: direct evidence for sulfur donor ligation trans to dioxygen and structural characterization using EXAFS spectroscopy

Dawson, John H., Kau, Lung Shan., Penner-Hahn, James E., Sono, Masanori., Eble, Kim Smith., Bruce, Grant S., Hager, Lowell P., Hodgson, Keith O.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 436 KB

english, 1986

28

Formation and structure of molecular O:P-F. Mass spectrometry, infrared spectra of the matrix isolated species and ab initio calculations

Ahlrichs, Reinhart., Becherer, Ralf., Binnewies, Michael., Borrmann, Horst., Lakenbrink, Michael., Schunck, Stephan., Schnoeckel, Hansgeorg.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 918 KB

english, 1986

29

Correction. Donor-Acceptor Interaction and the Peculiar Structures of Dications

Koch, Wolfram., Frenking, Gernot., Gauss, Jurgen., Cremer, Dieter.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 112 KB

english, 1986

30

Functionalized Keggin- and Dawson-type cyclopentadienyltitanium heteropolytungstate anions: small, individually distinguishable labels for conventional transmission electron microscopy. 1. Synthesis

Keana, John F. W., Ogan, Marc D.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.05 MB

english, 1986

31

3,4-Dimethylenefuran and 3,4-dimethylenethiophene, heterocyclic analogs of the disjoint non-Kekule hydrocarbon tetramethyleneethane

Stone, Keith J., Greenberg, Marc M., Goodman, Joshua L., Peters, Kevin S., Berson, Jerome A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 274 KB

english, 1986

32

Total synthesis of (+)-aplasmomycin

White, James D., Vedananda, Thalathani R., Kang, Myung Chol., Choudhry, Satish C.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 370 KB

english, 1986

33

Construction of an enzyme-targeted organophosphonate using immobilized enzyme and whole-cell synthesis

Reimer, L. M., Conley, D. L., Pompliano, D. L., Frost, J. W.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 877 KB

english, 1986

34

Differential anomalous x-ray scattering evidence for the existence of .mu.-H3O2- bridging ligands in solution

Lorentz, Robert D., Bino, Avi., Penner-Hahn, James E.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 310 KB

english, 1986

35

The triplex Diels-Alder reaction of indene and cyclic dienes

Calhoun, Glenn C., Schuster, Gary B.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 898 KB

english, 1986

36

Surprisingly efficient intramolecular addition of carbon radicals to carbonyl groups: a ready route to cycloalkanols

Tsang, Ray., Fraser-Reid, Bert.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 401 KB

english, 1986

37

Time-resolved observation of sequential bond cleavage in a gas-phase azoalkane

Adams, J. Stephen., Burton, Katherine A., Andrews, B. Kim., Weisman, R. Bruce., Engel, Paul S.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 548 KB

english, 1986

38

Electronic character of methylenecyclopropene: microwave spectrum, structure, and dipole moment

Norden, Timothy D., Staley, Stuart W., Taylor, William H., Harmony, Marlin D.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 924 KB

english, 1986

39

Phospholipids chiral at phosphorus. 12. Configurational effect on the thermotropic properties of chiral dipalmitoylthiophosphatidylcholine

Wisner, Daniel A., Rosario-Jansen, Theresa., Tsai, Ming Daw.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 634 KB

english, 1986

40

Masthead

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 152 KB

english, 1986

41

Kinetics of intermolecular oxidative addition of primary, secondary, and tertiary CH bonds to tricarbonylmanganate anion

McDonald, Richard N., Jones, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 308 KB

english, 1986

42

Enantioselective synthesis of .beta.-amino esters through high pressure-induced addition of amines to .alpha.,.beta.-ethylenic esters

D'Angelo, Jean., Maddaluno, Jacques.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 400 KB

english, 1986

43

Structure elucidation of the antibiotic desertomycin through the use of new two-dimensional NMR techniques

Bax, Ad., Aszalos, A., Dinya, Z., Sudo, K.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 962 KB

english, 1986

44

Absence of the metal-support interaction for nickel-titanium dioxide composites prepared by ion-exchange techniques

Zur Loye, Hans Conrad., Faltens, Tanya A., Stacy, Angelica M.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 311 KB

english, 1986

45

Correction. Gas Phase Nucleophilic Addition Reactions of Negative Ions with Transition Metal Carbonyls

Lane, Kelley R., Sallans, Larry., Squires, Robert R.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 112 KB

english, 1986

46

The cyclopropylmethyl free-radical clock. Calibration for the 30-89.degree. C range

Mathew, L., Warkentin, J.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 527 KB

english, 1986

47

Synthesis and x-ray structure of the first cluster-stabilized phosphaallene, [.mu.3-.eta.2-tert-BuP(C:CHPh)]FeCo2(CO)9

Mathieu, Rene., Caminade, Anne Marie., Majoral, Jean Pierre., Daran, Jean Claude.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 534 KB

english, 1986

48

Neutron profile refinement of the structure of FeOCl and FeOCl(TTF)1/8.5

Kauzlarich, S. M., Stanton, J. L., Faber, J., Averill, B. A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 741 KB

english, 1986

49

Synthesis of organometallic heterodinuclear .mu.-oxo complexes by extrusion of alkenes from zirconium/tungsten oxaalkyl complexes

Jacobsen, Eric N., Trost, Mary K., Bergman, Robert G.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 396 KB

english, 1986

50

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 286 KB

english, 1986

51

Ab initio calculations of the singlet-triplet energy separation in 3,4-dimethylenefuran and related diradicals

Du, Ping., Hrovat, David A., Borden, Weston Thatcher.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 309 KB

english, 1986

52

Origin of oxygen atoms in cantharidin biosynthesized by beetles

McCormick, John P., Carrel, James E., Doom, James P.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 556 KB

english, 1986

53

Dimerization energetics of benzene and aromatic amino acid side chains

Burley, S. K., Petsko, G. A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 634 KB

english, 1986

54

Neutral gas-phase analogs of condensed-phase post-transition-metal cluster ions: laser vaporization and photoionization of tin-bismuth and lead-antimony alloys

Wheeler, R. G., LaiHing, K., Wilson, W. L., Allen, J. D., King, R. B., Duncan, M. A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 315 KB

english, 1986

55

Reaction of Group 4 metal .eta.2-acyls with pyridine: formation of .alpha.,.alpha.-disubstituted-2,6-pyridinedimethoxide ligands

Fanwick, Phillip E., Kobriger, Lisa M., McMullen, Anne K., Rothwell, Ian P.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 467 KB

english, 1986

56

Correction. Biomimetic Models for Cysteine Proteases. 2. Nucleophilic Thiolate-Containing Zwitterions Produced from Imidazole-Thiol Pairs. A Model for the Acylation Step in Papain-Mediated Hydrolyses

Skorey, K I., Brown, R S.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 112 KB

english, 1986

57

cis-[Bis(dicyclohexylphosphino)ethane]platinum(0) reacts with unactivated carbon-hydrogen bonds

Hackett, Marifaith., Ibers, James A., Jernakoff, Peter., Whitesides, George M.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 306 KB

english, 1986

58

Triplet photoisomerization of 1-substituted 6-methoxybenzonorbornadienes. Excited-state competition between bridgehead and m-methoxy groups for intramolecular control of the dual channel di-.pi.-methane pathway. The vinyl deuterium isotope effect

Paquette, Leo A., Varadarajan, Aravamuthan., Burke, Lonnie D.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.15 MB

english, 1986

59

Correction. A Structural, Kinetic, and Thermodynamic Study of the Reversible Thermal C-H Activation/Reductive Elimination of Alkanes at Iridium

Buchanan, J M., Stryker, Jeffrey M., Bergman, Robert G.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 112 KB

english, 1986

60

Activation of benzene by a tetrakis(trimethylphosphine)osmium(II) system. Mechanism of activation

Desrosiers, Peter J., Shinomoto, Ronald S., Flood, Thomas C.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 990 KB

english, 1986

61

Double nitrogen inversion in sesquibicyclic hydrazines and their cation radicals

Nelsen, Stephen F., Frigo, Timothy B., Kim, Yaesil., Thompson-Colon, James A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.10 MB

english, 1986

62

The radical anion of homoazulene and its rearrangement products. An ESR and ENDOR study

Gerson, Fabian., Knoebel, Juergen., Metzger, Andre., Scott, Lawrence T., Kirms, Mark A., Oda, Mitsunori., Sumpter, Chris A.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 916 KB

english, 1986

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