Volume 109; Issue 4

Main
Journal of the American Chemical Society
Volume 109; Issue 4

Journal of the American Chemical Society

Volume 109; Issue 4

1

Nitrogen-15 labeled deoxynucleosides. Synthesis of 15N6-and 15N1-deoxyadenosines from deoxyadenosine

Gao, X., Jones, R. A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 389 KB

english, 1987

2

Acyclic stereocontrol in catalyzed intramolecular Diels-Alder cyclizations leading to octahydronaphthalenecarboxaldehydes

Marshall, James A., Grote, Jonathan, Audia, James E.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.22 MB

english, 1987

3

Absence of an isotope effect on the metalation of chiral formamidines. The mechanism of asymmetric alkylations leading to chiral amines

Meyers, A. I., Dickman, Daniel A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 364 KB

english, 1987

4

A stepwise mechanism for gas-phase unimolecular ion decompositions. Isotope effects in the fragmentation of tert-butoxide anion

Tumas, William, Foster, Robert F., Pellerite, Mark J., Brauman, John I.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.31 MB

english, 1987

5

Theoretical analysis of hydrocarbon properties. 2. Additivity of group properties and the origin of strain energy

Wiberg, Kenneth B., Bader, Richard F. W., Lau, Clement D. H.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.59 MB

english, 1987

6

Monte Carlo simulations of small ion-pair hydrate clusters: hydrated lithium nitrite (NO2-:Li+(H2O)n)

Banerjee, Ajit, Quigley, Alice, Frey, Regina F., Johnson, Dana, Simons, Jack

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 684 KB

english, 1987

7

Synthesis and Claisen rearrangement of alkoxyallyl enol ethers. Evidence for a dipolar transition state

Coates, Robert M., Rogers, Brian D., Hobbs, Steven J., Curran, Dennis P., Peck, David R.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.58 MB

english, 1987

8

Kinetics, stereochemistry, and mechanism of interaction of Vaska's complex with ethynylvinyl triflates. Formation of novel .sigma.-butatrienyliridium compounds

Stang, Peter J., Dixit, Vandana, Schiavelli, Melvyn D., Drees, Paul

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 891 KB

english, 1987

9

Structure of brevetoxin A as constructed from NMR and mass spectral data

Pawlak, Jan, Tempesta, Michael S., Golik, Jerzy, Zagorski, Michael G., Lee, Min S., Nakanishi, Koji, Iwashita, Takashi, Gross, Michael L., Tomer, Kenneth B.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 818 KB

english, 1987

10

A remarkable steric effect in palladium-catalyzed Grignard coupling: regio- and stereoselective monoalkylation and -arylation of 1,1-dichloro-1-alkenes

Minato, Akio, Suzuki, Keizo, Tamao, Kohei

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 282 KB

english, 1987

11

The effects of various substituents upon the properties of the bond between the bridgehead carbons in bicyclobutane

Politzer, Peter, Kirschenheuter, Gary P., Alster, Jack

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 589 KB

english, 1987

12

Magnetic properties in terms of localized quantities. 5. Carbocations

Schindler, Michael

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.31 MB

english, 1987

13

Asymmetric synthesis of (1'R,3R,4R)-4-acetoxy-3-[1'-((tert-butyldimethylsilyl)oxy)ethyl]-2-azetidinone and other 3-(1'-hydroxyethyl)-2-azetidinones from (S)-(+)-ethyl 3-hydroxybutanoate: formal total synthesis of (+)-thienamycin

Georg, Gunda I., Kant, Joydeep, Gill, Harpal S.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 981 KB

english, 1987

14

Azidocubanes. 1. Photolysis: formation of a homoprismyl nitrile

Eaton, Philip E., Hormann, Robert E.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 299 KB

english, 1987

15

The mechanism of rearrangement of chorismic acid and related compounds

Gajewski, Joseph J., Jurayj, Jurjus, Kimbrough, Doris R., Gande, Matthew E., Ganem, Bruce, Carpenter, Barry K.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 2.34 MB

english, 1987

16

Inverse phase-transfer catalysis: probing its mechanism with competitive transacylation

Fife, Wilmer K., Xin, Yue

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 269 KB

english, 1987

17

Theoretical analysis of hydrocarbon properties. 1. Bonds, structures, charge concentrations, and charge relaxations

Wiberg, Kenneth B., Bader, Richard F. W., Lau, Clement D. H.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 4.77 MB

english, 1987

18

Synthesis and molecular structure of (Z)-[6]Paracycloph-3-enes

Tobe, Yoshito, Ueda, Kenichi, Kaneda, Teruhisa, Kakiuchi, Kiyomi, Odaira, Yoshinobu, Kai, Yasushi, Kasai, Nobutami

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.13 MB

english, 1987

19

Evidence for diazenyl diradicals in the photoisomerization of 4-methylene-3,3,5,5-tetramethylpyrazoline

Adam, Waldemar, Doerr, Markus

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 281 KB

english, 1987

20

Redox chemistry of tetrakis(1-norbornyl)cobalt. Synthesis and characterization of a cobalt(V) alkyl and self-exchange rate of a Co(III)/Co(IV) couple

Byrne, Erin K., Theopold, Klaus H.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 291 KB

english, 1987

21

Correction. Polyene Cyclization Strategy in the Stereospecific Synthesis of B/C-trans-Morphinan. A Total Synthesis of (±)-O-Methylpallidinine

Kano, Shinzo, Yokomatsu, Tsutomu, Nemoto, Hajime, Shibuya, Shiroshi

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

22

Dioxygen-copper reactivity: EXAFS studies of a peroxo-dicopper(II) complex

Blackburn, Ninian J., Strange, Richard W., Cruse, Richard W., Karlin, Kenneth D.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 388 KB

english, 1987

23

Ab initio localized electron calculations on solvated electron structures

Clark, Timothy, Illing, Gerd

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 900 KB

english, 1987

24

Correction. Rotational Preference in "Cage" Dissociation-Recombinations: Thermal Automerization of Optically Active Methyl threo-2,3-Diphenylbutane-2-carboxylate

von E. Doering, W, Birladeanu, Ludmila

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

25

Stereospecific oxygenation of 3-adamantylidenetricyclo[3.2.1.02,4]octane: singlet oxygen vs. electron-transfer oxygenations

Akasaka, Takeshi, Ando, Wataru

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 399 KB

english, 1987

26

Oxygen-17 NMR spectroscopy: torsion angle relationships in aryl carboxylic esters, acids and amides

Baumstark, A. L., Balakrishnan, P., Dotrong, M., McCloskey, C. J., Oakley, M. G., Boykin, D. W.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 489 KB

english, 1987

27

Electrochemical studies of rhodium-carbonbond formation. The reaction of monomeric (tetraphenylporphinato)rhodium(II) with alkyl and aryl halides

Anderson, J. E., Yao, C. L., Kadish, K. M.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 698 KB

english, 1987

28

Kinetics and mechanism of aminium salt-initiated cycloadditions

Lorenz, Kurt T., Bauld, Nathan L.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 517 KB

english, 1987

29

Spectroscopic studies of the binuclear ferrous active site of deoxyhemerythrin: coordination number and probable bridging ligands for the native and ligand-bound forms

Reem, Richard C., Solomon, Edward I.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.49 MB

english, 1987

30

The mechanism of directed second lithiations: detection of short proton-lithium separations by 6Li-1H HOESY (2D-heteronuclear Overhauser spectroscopy)

Bauer, Walter, Clark, Timothy, Schleyer, Paul v. R.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 744 KB

english, 1987

31

Correction. Medicinal Chemistry: The Role of Organic Chemistry in Drug Research

Hoekstra, Marvin

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

32

s-Cis vs. gauche 1,3-butadiene: evidence for planarity from polarized matrix-isolation IR spectroscopy

Fisher, Jeffrey J., Michl, Josef

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 558 KB

english, 1987

33

Thermodynamic control in the asymmetric alkylation of the dipole-stabilized anions of chiral aminooxazolines

Gawley, Robert E.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 275 KB

english, 1987

34

Gas-phase observation and carbon monoxide substitution of cis-Cr(CO)4 (C2H4)2 by time-resolved IR absorption spectrometry

Weiller, Bruce H., Grant, Edward R.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 294 KB

english, 1987

35

Nonenzymatic sequence-specific cleavage of single-stranded DNA to nucleotide resolution. DNA methyl thioether probes

Iverson, Brent L., Dervan, Peter B.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 842 KB

english, 1987

36

Bruceantin support studies. 12. Synthesis of a pentacyclic ABCDE bruceantin intermediate

Kuo, Fengjiun, Fuchs, P. L.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 863 KB

english, 1987

37

Correction. An Approach toward the Complete FAB Analysis of Enzymic Digests of Peptides and Proteins

Naylor, S, Findeis, A. Frederick, Gibson, Bradford, Williams, Dudley

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

38

Preparation and conformation of (E,E)-1,5-cyclooctadiene

Boeckh, Dieter, Huisgen, Rolf, Noeth, Heinrich

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 297 KB

english, 1987

39

Correction. Metal Atom Reactions with Methane. Boron, Aluminum, Gallium, and Indium Atoms and Dimers

Jeong, GiHo, Klabunde, Kenneth

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

40

Radical cations. 3. Photoreactions of biacetyl, benzophenone, and benzil with electron-rich alkenes

Gersdorf, Joachim, Mattay, Jochen, Goerner, Helmut

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 884 KB

english, 1987

41

Correction. Electron Affinities of Di- and Triacyanoethylene and Cyanobenzenes Based on Measurement sof Gas-Phase Electron-Transfer Equilibria

Chowdhury, Swapan, Kebarle, Paul

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

42

Theoretical study of structures and relative energies of isomeric metalated acetaldoximes, models for metalated oxime ethers

Glaser, Rainer, Streitwieser, Andrew

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 423 KB

english, 1987

43

1,2-Asymmetric rearrangements in chiral sulfinylcyclopropane systems: asymmetric synthesis of .alpha.,.alpha.-disubstituted cyclobutanones

Hiroi, Kunio, Nakamura, Hironori, Anzai, Takashi

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 269 KB

english, 1987

44

Masthead

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 145 KB

english, 1987

45

Macrolide biosynthesis. Tylactone formation involves the processive addition of three carbon units

Yue, Stephen, Duncan, Janice S., Yamamoto, Yoshikuni, Hutchinson, C. Richard

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 459 KB

english, 1987

46

Langmuir-Blodgett ultrathin membranes of fumarate polymers

Shigehara, Kiyotaka, Hara, Masahiko, Nakahama, Hidenari, Miyata, Seizo, Murata, Yoshishige, Yamada, Akira

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 265 KB

english, 1987

47

Correction. Heavy-Atom Kinetic Isotope Effects in the Acid-Catalyzed Rearrangement of N-Naphthyl-N'-Phenylhydrazine. Rearrangement Is Shown To Be A Concerted Process

Shine, Henry, Kupczyk-Subotkowska, Lydia, Subotkowski, Witold

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 99 KB

english, 1987

48

Why does nature not use the porphyrin ligand in vitamin B12?

Geno, Maureen K., Halpern, Jack

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 402 KB

english, 1987

49

Model complexes for the cis-ruthenium(VI)-dioxo system. Novel chemistry of [RuIII(N4O)(OH2)][ClO4]2 (N4OH = bis[2-(2-pyridyl)ethyl][2-hydroxy-2-(2-pyridyl)ethyl]amine)

Che, Chi Ming, Yam, Vivian Wing Wah

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 230 KB

english, 1987

50

Protein structure and interactions by combined use of sequential NMR assignments and isotope labeling

Senn, Hans, Otting, Gottfried, Wuethrich, Kurt

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 387 KB

english, 1987

51

Magnetic interaction of two diphenylcarbene units linked with an ethylenic double bond

Murata, Shigeru, Sugawara, Tadashi, Iwamura, Hiizu

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 273 KB

english, 1987

52

Free radical alkylthiylation of hydridophosphoranes. Structure-reactivity factors affecting the reactions of bicyclic phosphoranyl radicals with disulfides

Bentrude, Wesley G., Kawashima, Takayuki, Keys, Boyd A., Garroussian, Massoud, Heide, Wilfried, Wedegaertner, Donald A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.18 MB

english, 1987

53

Fast halogen abstractions from alkyl halides by alkyl radicals. Quantitation of the processes occurring in and a caveat for studies employing alkyl halide mechanistic probes

Newcomb, Martin, Sanchez, Robert M., Kaplan, Jere

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 705 KB

english, 1987

54

A comparison of electron donor and proton abstraction activities of thermally activated pure magnesium oxide and doped magnesium oxides

Klabunde, Kenneth J., Matsuhashi, Hiromi

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 528 KB

english, 1987

55

External heavy-atom effects on first and second order decay rate constants of anthracene triplets

Saltiel, Jack, Ganapathy, Srinivasan, Atwater, Beauford W.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.00 MB

english, 1987

56

Membrane-enclosed enzymic catalysis (MEEC): a useful, practical new method for the manipulation of enzymes in organic synthesis

Bednarski, Mark D., Chenault, H. Keith, Simon, Ethan S., Whitesides, George M.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 319 KB

english, 1987

57

The (phthalocyaninato)copper iodide complex Cu(pc)I: a molecular metal with a one-dimensional array of local moments embedded in a "Fermi sea" of charge carriers

Ogawa, Michael Y., Martinsen, Jens, Palmer, Sharon M., Stanton, Judith L., Tanaka, Jiro, Greene, Richard L., Hoffman, Brian M., Ibers, James A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 882 KB

english, 1987

58

Micromodulation: induction of intramolecular electron transfer by solvate molecule dynamics in the iron acetato oxo methylpyridine mixed-valence complex [Fe3O(O2CCH3)6(3-Me-py)3](solvate)

Oh, Seung Mo, Wilson, Scott R., Hendrickson, David N., Woehler, Scott E., Wittebort, Richard J., Inniss, Daryl, Strouse, Charles E.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 2.05 MB

english, 1987

59

Deuteron NMR study of lattice dynamics affecting the rate of intramolecular electron transfer in the iron acetato oxo pyridine mixed-valence complex [Fe3O(O2CCH3)6(py)3](py)

Woehler, Scott E., Wittebort, Richard J., Oh, Seung M., Kambara, Takeshi, Hendrickson, David N., Inniss, Daryl, Strouse, Charles E.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.22 MB

english, 1987

60

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 672 KB

english, 1987

61

Macrolide biosynthesis. 4. Intact incorporation of a chain-elongation intermediate into erythromycin.

Cane, David E., Yang, Chi Ching

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 367 KB

english, 1987

62

Fluorides and fluoro acids. 14. Crystal structures of acid hydrates and oxonium salts. 24. First examples of type I clathrate hydrates of strong acids: polyhydrates of hexafluorophosphoric, tetrafluoroboric, and perchloric acid

Mootz, Dietrich, Oellers, Ernst Josef, Wiebcke, Michael

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 384 KB

english, 1987

63

Total synthesis of (+)-phyllanthocin

Smith, Amos B., Fukui, Mineo

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 476 KB

english, 1987

64

Gas-phase organometallic kinetics. 2. Dissociative substitution kinetics of Fe(CO)2(C2H4)3 by transient IR absorption spectrometry

Weiller, Bruce H., Grant, Edward R.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 613 KB

english, 1987

65

Unexpected diversity in the coordination chemistry of tartrate esters with titanium(IV)

Pedersen, Steven F., Dewan, John C., Eckman, Richard R., Sharpless, K. Barry

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 427 KB

english, 1987

66

Photochemical activation of acylated .alpha.-thrombin

Turner, A. D., Pizzo, S. V., Rozakis, G. W., Porter, N. A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 285 KB

english, 1987

67

Synthesis of amino-.beta.-lactams by the photolytic reaction of imines with pentacarbonyl[(dibenzylamino)carbene]chromium(0)

Borel, Christian, Hegedus, Louis S., Krebs, Jurg, Satoh, Yoshitaka

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 724 KB

english, 1987

68

A novel hypervalent antimony ate complex (12-Sb-6)

Akiba, Kinya, Fujikawa, Hisao, Sunaguchi, Yuka, Yamamoto, Yohsuke

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 391 KB

english, 1987

69

Biosynthesis of the modified peptide antibiotic nosiheptide in Streptomyces actuosus

Houck, David R., Chen, Li Chun, Keller, Paul J., Beale, John M., Floss, Heinz G.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 342 KB

english, 1987

70

Theoretical study of hydridocobalt carbonyls

Antolovic, Danko, Davidson, Ernest R.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 1.09 MB

english, 1987

71

Total synthesis of (+)-phyllanthoside

Smith, Amos B., Rivero, Ralph A.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 421 KB

english, 1987

72

Photochemistry of (5,10,15,20-tetraphenylporphyrinato)iron(III) halide complexes, Fe(TPP)(X)

Hendrickson, David N., Kinnaird, Michael G., Suslick, Kenneth S.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 278 KB

english, 1987

73

Bimolecular reactions of doubly charged metal ions in the gas phase. Formation of NbCH22+

Buckner, Steven W., Freiser, Ben S.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 274 KB

english, 1987

74

Interconversion of conformation of apomyoglobin adsorbed on hydrophobic silica gel

Lochmueller, C. H., Saavedra, Steven S.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 287 KB

english, 1987

75

Effect of ligand on ring contraction of six-membered nickel-containing cyclic esters, LnNiCH2CH2CH2COO, to their five-membered-ring isomers, LnNiCH(CH3)CH2COO. Kinetic and thermodynamic control of asymmetric induction by chiral diphosphines in the ring contraction

Yamamoto, Takakazu, Sano, Kenji, Yamamoto, Akio

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 967 KB

english, 1987

76

SINDO1 study of the photoisomerization of 2-methylfuran to 3-methylfuran

Buss, Sabine, Jug, Karl

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 729 KB

english, 1987

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