Volume 110; Issue 22

Main
Journal of the American Chemical Society
Volume 110; Issue 22

Journal of the American Chemical Society

Volume 110; Issue 22

1

Synthesis, crystal structures, reactivity, and magnetochemistry of a series of binuclear complexes of manganese(II), -(III), and -(IV) of biological relevance. The crystal structure of [L'MnIV(.mu.-O)3MnIVL'](PF6)2.H2O containing an unprecedented short Mn.cntdot..cntdot..cntdot.Mn distance of 2.296 .ANG.

Wieghardt, Karl., Bossek, Ursula., Nuber, Bernhard., Weiss, Johannes., Bonvoisin, J., Corbella, M., Vitols, S. E., Girerd, J. J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.66 MB

english, 1988

2

Vicinal diol cyclic sulfates. Like epoxides only more reactive

Gao, Yun., Sharpless, K. Barry.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 308 KB

english, 1988

3

Catalytic organometallic chemistry in water: the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives

Novak, Bruce M., Grubbs, Robert H.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 327 KB

english, 1988

4

Structural and theoretical models of photosynthetic chromophores. Implications for redox, light-absorption properties and vectorial electron flow

Barkigia, K. M., Chantranupong, L., Smith, K. M., Fajer, J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 278 KB

english, 1988

5

Carbon dioxide-laser desorption and multiphoton ionization of tris(2,2'-bipyridyl)ruthenium

Beavis, Ronald., Lindner, Josef., Grotemeyer, Juergen., Atkinson, Ian M., Keene, F. Richard., Knight, Alan E. W.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 301 KB

english, 1988

6

Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 2. Use of the trans-2,trans-3-diphenylcyclopropyl substituent in a search for radical intermediates

Castellino, Angelo J., Bruice, Thomas C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.03 MB

english, 1988

7

Two regiocomplementary approaches to angular furanocoumarins with chromium carbene complexes: synthesis of sphondin, thiosphondin, heratomin, and angelicin

Wulff, William D., McCallum, J. Stuart., Kunng, Fen Ann.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.90 MB

english, 1988

8

Thermochromism in copper(II) halide salts. 4. Bis(diethylammonium)tetrachlorocuprate(II), structure of the high-temperature phase and physical characterization of its two phases

Bloomquist, Darrell R., Pressprich, Mark R., Willett, Roger D.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.04 MB

english, 1988

9

Activation of a metal axial ligand bond in aluminum porphyrin by visible light

Hirai, Yasuhiro., Murayama, Hideki., Aida, Takuzo., Inoue, Shohei.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 489 KB

english, 1988

10

The C4H7+ cation. A theoretical investigation

Koch, Wolfram., Liu, Bowen., DeFrees, Douglas J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 523 KB

english, 1988

11

A new model for the oxygen-evolving complex in photosynthesis. A trinuclear .mu.3-oxomanganese(III) complex which contains a .mu.-peroxo group

Bhula, Rajumati., Gainsford, Graeme J., Weatherburn, David C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 421 KB

english, 1988

12

Kinetics of the anion-catalyzed Michael reaction of silyl ketene acetals. Initiation and propagation steps of group transfer polymerization

Brittain, William J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 644 KB

english, 1988

13

A physical basis for the VSEPR model of molecular geometry

Bader, Richard F. W., Gillespie, Ronald J., MacDougall, Preston J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 2.03 MB

english, 1988

14

Nucleophilic addition to olefins. Part 23. High intrinsic rate constant and large imbalances in the thiolate ion addition to substituted .alpha.-nitrostilbenes

Bernasconi, Claude F., Killion, Robert B.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 929 KB

english, 1988

15

.alpha.-Amino acids as chiral educts for asymmetric products. Alkylation of N-phenylfluorenyl .alpha.-amino ketones. Synthesis of optically pure .alpha.-alkyl carboxylic acids

Lubell, William D., Rapoport, Henry.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.24 MB

english, 1988

16

A highly stereocontrolled, four-step synthesis of (.+-.)-lasubine II

Brown, Jack D., Foley, Michael A., Comins, Daniel L.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 436 KB

english, 1988

17

Total synthesis of octosyl acid A. Intramolecular Williamson reaction via a cyclic stannylene derivative

Danishefsky, Samuel J., Hungate, Randall., Schulte, Gayle.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 854 KB

english, 1988

18

Sulfur-sulfur bond lengths, or can a bond length be estimated from a single parameter?

Knop, Osvald., Boyd, Russell J., Choi, S. C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 388 KB

english, 1988

19

Chemical reactivity of the three-sulfur ring in norbornanetrithiolanes. The S3 transfer reaction

Ghosh, Tirthankar., Bartlett, Paul D.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 996 KB

english, 1988

20

Mechanism of aromatic hydroxylation in the Fenton and related reactions. One-electron oxidation and the NIH shift

Kurata, Tsunehiko., Watanabe, Yasumasa., Katoh, Makoto., Sawaki, Yasuhiko.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 904 KB

english, 1988

21

Facile stereoselective allylic hydroxylation by dopamine .beta.-monooxygenase

Sirimanne, Sarath R., May, Sheldon W.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 321 KB

english, 1988

22

Nitrogen protonation of N-nitrosodimethylamine

Keefer, Larry K., Hrabie, Joseph A., Hilton, Bruce D., Wilbur, David.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 603 KB

english, 1988

23

Direct observational studies of a singlet alkylcarbene: methylmethoxycarbene, a remarkably selective nucleophile

Sheridan, R. S., Moss, R. A., Wilk, B. K., Shen, S., Wlostowski, M., Kesselmayer, M. A., Subramanian, R., Kmiecik-Lawrynowicz, G., Krogh-Jespersen, K.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 322 KB

english, 1988

24

Electronic spectroscopy of small tryptophan peptides in supersonic molecular beams

Cable, J. R., Tubergen, Michael J., Levy, Donald H.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1002 KB

english, 1988

25

Design and chemical synthesis of a sequence-specific DNA-cleaving protein

Mack, David P., Iverson, Brent L., Dervan, Peter B.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 957 KB

english, 1988

26

Proton transfer reactions of sulfonium ylides: unit Broensted slopes do not require diffusion-controlled proton transfer

Murray, Christopher J., Jencks, William P.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 443 KB

english, 1988

27

2,5,7,7-Tetraphenyl-7-boratabicyclo[4.1.0]hepta-2,4-diene: the first isolation and characterization of a boratanorcaradiene

Wilkey, John D., Schuster, Gary B.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 444 KB

english, 1988

28

Does a stilbazolium cation adsorbing poly(styrenesulfonate) anion form micellelike clusters?

Takagi, Katsuhiko., Fukaya, Haruhiko., Sawaki, Yasuhiko.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 486 KB

english, 1988

29

Nitrogen quadrupole coupling in cyclopentadienyl nickel nitrosyl

Kukolich, S. G., Rund, J. V., Pauley, D. J., Bumgarner, R. E.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 292 KB

english, 1988

30

Cycloalkylmethyl radicals. 6. The unexpectedly high barrier to the rotation of axial CH2.cntdot. groups in cyclohexylmethyl radicals

Hughes, L., Ingold, K. U., Walton, J. C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 822 KB

english, 1988

31

A carotenoid-diporphyrin-quinone model for photosynthetic multistep electron and energy transfer

Gust, Devens., Moore, Thomas A., Moore, Ana L., Makings, Lewis R., Seely, Gilbert R., Ma, Xiaochun., Trier, Todd T., Gao, Feng.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 440 KB

english, 1988

32

Perforated monolayers: porous and cohesive monolayers from mercurated calix[6]arenes

Markowitz, Michael A., Bielski, Roman., Regen, Steven L.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 862 KB

english, 1988

33

Masthead

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 271 KB

english, 1988

34

C-H bond activation in Cp2ZrIIICH2PPh2: evidence for an unexpected mechanistic pathway

Blandy, Claudine., Locke, Susan A., Young, Steven J., Schore, Neil E.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 413 KB

english, 1988

35

Trans-edge-sharing molybdenum octahedra: a reciprocal space approach to metal-metal bonding in finite chains

Wheeler, Ralph A., Hoffmann, Roald.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.21 MB

english, 1988

36

H+-induced release of contents of phosphatidylcholine vesicles bearing surface-bound polyelectrolyte chains

Maeda, Mizuo., Kumano, Atsushi., Tirrell, David A.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 694 KB

english, 1988

37

Ab initio calculations of the geometries and IR spectra of two derivatives of tetramethyleneethane

Choi, Yeong., Jordan, Kenneth D., Paik, Yi Hyon., Chang, Wonghil., Dowd, Paul.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 202 KB

english, 1988

38

Heats of formation of alkyl radicals from appearance energies

Holmes, John L., Lossing, F. P., Maccoll, Allan.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 395 KB

english, 1988

39

The preparation and crystal structures of new platinum/phosphonate complexes

Bau, Robert., Huang, Sharon K. S., Feng, Jin An., McKenna, Charles E.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.47 MB

english, 1988

40

Dioxetane formation at a double bond adjacent to bridgehead nitrogen: rapid reaction between neostrychnine and singlet oxygen in a polar protic medium. Evidence against the intermediacy of an open zwitterion

Curtis, N. M., Gorman, A. A., Prescott, A. L.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 295 KB

english, 1988

41

Photooxidation of (.eta.5-C5H5)[P(OMe)3]2Mo.tplbond.CPh in CHCl3. Intermediacy of a 17-electron cationic metal carbyne

Leep, Carolyn J., Kingsbury, Kevin B., McElwee-White, Lisa.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 315 KB

english, 1988

42

Synthesis and stabilization of tantalum-coordinated dihydroxyacetylene from two reductively coupled carbon monoxide ligands

Vrtis, Raymond N., Rao, C. Pulla., Bott, Simon G., Lippard, Stephen J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.08 MB

english, 1988

43

Effect of pressure on the proton-proton vicinal coupling constants in 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane-1-13C. A new approach to high-pressure study of molecular conformations

Yamada, H., Kazuoka, T., Sera, A.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 259 KB

english, 1988

44

The dynamics of reaction of a water-soluble and non-.mu.-oxo dimer forming iron(III) porphyrin with tert-butyl hydroperoxide in aqueous solution. 1. Studies using a trap for immediate oxidation products

Smith, John R. Lindsay., Balasubramanian, P. N., Bruice, Thomas C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1009 KB

english, 1988

45

Heats of formation and bond dissociation energies in halogen-substituted methyl and ethyl radicals

Holmes, John L., Lossing, F. P.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 389 KB

english, 1988

46

Preparation, isolation, and characterization of transition-metal .eta.2-silene complexes. X-ray crystal structure of (.eta.5-C5Me5)[P(iso-Pr)3]Ru(H)(.eta.2-CH2SiPh2)

Campion, Brian K., Heyn, Richard H., Tilley, T. Don.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1021 KB

english, 1988

47

Hydrolysis of a peptide bond in neutral water

Kahne, Daniel., Still, W. Clark.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 882 KB

english, 1988

48

Ruthenium(II) 2,2'-bipyridine complexes containing methyl isocyanide ligands. Extreme effects of nonchromophoric ligands on excited-state properties

Indelli, Maria Teresa., Bignozzi, Carlo Alberto., Marconi, Anna., Scandola, Franco.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 801 KB

english, 1988

49

Protonation of 1,3,5-triaminobenzenes in aqueous solutions. Thermodynamics and kinetics of the formation of stable .sigma.-complexes

Knoche, Wilhelm., Schoeller, Wolfgang W., Schomaecker, Reinhard., Vogel, Siegmund.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 686 KB

english, 1988

50

Multiple electron oxidation of phenols by an oxo complex of ruthenium(IV)

Seok, Won K., Meyer, Thomas J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.14 MB

english, 1988

51

Free standing polydiacetylene films cast from bilayer membranes

Kuo, Thauming., O'Brien, David F.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 293 KB

english, 1988

52

A new structural form of tin as a double cube. A heptanuclear tin-sulfur cluster

Swamy, K. C. Kumara., Day, Roberta O., Holmes, Robert R.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 303 KB

english, 1988

53

Intermolecular electronic interactions in the primary charge separation in bacterial photosynthesis

Plato, M., Moebius, K., Michel-Beyerle, M. E., Bixon, M., Jortner, Joshua.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 899 KB

english, 1988

54

Fragmentation of the enolate ions of some cycloalkanones. A comparison of high-energy and low-energy collisional activation

Chowdhury, Swapan., Harrison, Alex G.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 547 KB

english, 1988

55

Crystal and molecular structure of cis-[Pt(NH3)2[d(pGpG)]], the principal adduct formed by cis-diamminedichloroplatinum(II) with DNA

Sherman, Suzanne E., Gibson, Dan., Wang, Andrew H. J., Lippard, Stephen J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 2.89 MB

english, 1988

56

Structure-activity relations of (2-chloroethyl)nitrosoureas. 2. Kinetic evidence of a novel mechanism for the cytotoxically important DNA cross-linking reactions of (2-chloroethyl)nitrosoureas

Buckley, Neil., Brent, Thomas P.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.16 MB

english, 1988

57

Stereodynamics of N-ethyl-N-methyl-2-aminobutane

Danehey, Charles T., Grady, Gilbert L., Bonneau, Philippe R., Bushweller, C. Hackett.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.15 MB

english, 1988

58

.pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines

Harman, W. Dean., Taube, Henry.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 440 KB

english, 1988

59

Empirical potential energy surfaces relating structure and activation energy. 2. Determination of transition-state structure for the spontaneous hydrolysis of axial tetrahydropyranyl acetals

Buergi, Hans Beat., Dubler-Steudle, Katharina C.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.14 MB

english, 1988

60

Synthesis of the transient formyl complex [CH3N(PF2)2]3Co2(CO)(CHO)- and observation of facile formyl decomposition to give the mixed-valence complex [CH3N(PF2)2]3Co2(CO)2.cntdot.-

Dumond, David S., Richmond, Michael G.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.06 MB

english, 1988

61

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1009 KB

english, 1988

62

MM2/MOMM force-field parameters for azoalkanes

Kao, J., Leister, D.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 752 KB

english, 1988

63

Nucleophilic attacks on low LUMO compounds. Part 5. Radical-anionic nature of the transition state in the Michael addition reaction

Gross, Zeev., Hoz, Shmaryahu.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 680 KB

english, 1988

64

Permeability characteristics of lipid bilayers from lipoic acid-derived phosphatidylcholines. Comparison of monomeric, crosslinked and noncrosslinked polymerized membranes

Stefely, James., Markowitz, Michael A., Regen, Steven L.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1004 KB

english, 1988

65

EPR spectral evidence for a dinuclear active site in the Lactobacillus plantarum manganese catalase

Fronko, Richard M., Penner-Hahn, James E., Bender, Christopher J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 302 KB

english, 1988

66

Atom-transfer annulations in heterocycle synthesis. An efficient synthesis of (-)-trachelanthamidine and related ring systems

Jolly, Ravinder S., Livinghouse, Tom.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 421 KB

english, 1988

67

A reciprocal space approach to the orbitals of truncated crystals

Wheeler, Ralph A., Piela, Lucjan., Hoffmann, Roald.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 1.78 MB

english, 1988

68

Formation of cyclohexadienyl-type radicals in the photoreduction of xanthone as studied by a laser photolysis-ESR technique

Sakaguchi, Yoshio., Hayashi, Hisaharu., Murai, Hisao., Ihaya, Yasumasa J.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 850 KB

english, 1988

69

Measurement of 13C relaxation times in proteins by two-dimensional heteronuclear 1H-13C correlation spectroscopy

Nirmala, N. R., Wagner, Gerhard.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 271 KB

english, 1988

70

Relative energies of silaethylene and methylsilylene

Grev, Roger S., Scuseria, Gustavo E., Scheiner, Andrew C., Schaefer, Henry F., Gordon, Mark S.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 422 KB

english, 1988