Volume 114; Issue 9

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Journal of the American Chemical Society
Volume 114; Issue 9

Journal of the American Chemical Society

Volume 114; Issue 9

1

Nature of the reactive intermediates from the iron-induced activation of hydrogen peroxide: agents for the ketonization of methylenic carbons, the monooxygenation of hydrocarbons, and the dioxygenation of aryl olefins

Tung, Hui Chan, Kang, Chan, Sawyer, Donald T.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.33 MB

english, 1992

2

Alkali metal atom induced acetylene-vinylidene rearrangement: matrix isolation ESR study

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 890 KB

english, 1992

3

Homoconjugation and transannular orbital interactions detected by photoelectron and carbon-13 NMR spectroscopy. Bicyclo[3.3.1]nona-3,7-diene-2,6-dione and bicyclo[3.3.1]nonane-2,6-dione

Doerner, Thomas, Gleiter, Rolf, Robbins, Timothy A., Chayangkoon, Paochai, Lightner, David A.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.42 MB

english, 1992

4

Unwinding of supercoiled DNA by platinum-ethidium and related complexes

Keck, Michael V., Lippard, Stephen J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.12 MB

english, 1992

5

Epibatidine: a novel (chloropyridyl)azabicycloheptane with potent analgesic activity from an Ecuadoran poison frog

Spande, Thomas F., Garraffo, Hugo Martin, Edwards, Michael W., Yeh, Herman J. C., Pannell, Lewis, Daly, John W.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 520 KB

english, 1992

6

Synthesis, vapor growth, polymerization, and characterization of thin films of novel diacetylene derivatives of pyrrole. The use of computer modeling to predict chemical and optical properties of these diacetylenes and poly(diacetylenes)

Paley, M. S., Frazier, D. O., Abeledeyem, H., McManus, S. P., Zutaut, S. E.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 697 KB

english, 1992

7

Stereoselective covalent binding of aquaruthenium(II) complexes to DNA

Grover, Neena, Gupta, Nishi, Thorp, H. Holden

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 994 KB

english, 1992

8

Dynamics of electron hopping in assemblies of redox centers. Percolation and diffusion

Blauch, David N., Saveant, Jean Michel

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.30 MB

english, 1992

9

In pursuit of cyclopropanethione: cyclopropanethione S-oxide and S,S-dioxide

Block, Eric, Schwan, Adrian, Dixon, David A.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.03 MB

english, 1992

10

The deceptively simple thermolysis of trivalent permethyltitanocene derivatives (.eta.5-C5Me5)2TiR. Formation of a tetramethylfulvene titanium compound (.eta.6-C5Me4CH2)(.eta.5-C5Me5)Ti and RH, catalyzed by permethyltitanocene hydride, (.eta.5-C5Me5)2TiH

Luinstra, Gerrit A., Teuben, Jan H.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 983 KB

english, 1992

11

A new class of organocopper and organocuprate compounds derived from copper(I) arenethiolates

Knotter, D. Martin, Grove, David M., Smeets, Wilberth J. J., Spek, Anthony L., Van Koten, Gerard

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.42 MB

english, 1992

12

Electron-transfer kinetics in organized thiol monolayers with attached pentaammine(pyridine)ruthenium redox centers

Finklea, Harry O., Hanshew, Dwight D.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.66 MB

english, 1992

13

Crystallographic and thermodynamic comparison of natural and synthetic ligands bound to streptavidin

Weber, P. C., Wendoloski, J. J., Pantoliano, M. W., Salemme, F. R.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.06 MB

english, 1992

14

Spin and reaction dynamics in flexible polymethylene biradicals as studied by EPR, NMR, optical spectroscopy, and magnetic field effects. Measurements and mechanisms of scalar electron spin-spin coupling

Closs, Gerhard L., Forbes, Malcolm D. E., Piotrowiak, Piotr

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.16 MB

english, 1992

15

The surface nature of Grignard reagent formation

Walborsky, H. M., Topolski, Marek

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 731 KB

english, 1992

16

Synthesis and characterization of rhenium(VII) alkylidene alkylidyne complexes of the type Re(CR')(CHR')(OR)2 and related species

Toreki, Robert, Schrock, Richard R., Davis, William M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 3.37 MB

english, 1992

17

Theoretical study of the kinetic barriers in dihydrogen-exchange reactions

McKee, M. L., Stanbury, D. M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 777 KB

english, 1992

18

New synthesis, crystal structure, and vibrational spectra of tetramethylammonium azide and reactions of the fluoride anion with hydrazoic acid and of the azide anion with hydrogen fluoride

Christe, Karl O., Wilson, William W., Bau, Robert, Bunte, Steven W.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 503 KB

english, 1992

19

Solvent isotope effects on retinal cis-trans isomerization in the dark adaptation of bacteriorhodopsin

Seltzer, Stanley

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 732 KB

english, 1992

20

Low-temperature growth of the infinite layer phase of strontium copper oxide, SrCuO2, by pulsed laser deposition

Niu, Chunming, Lieber, Charles M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 302 KB

english, 1992

21

Intermolecular forces in organic clusters

Meot-Ner, Michael

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1015 KB

english, 1992

22

Unusual reactivity of bent acenes: reactions of [6](1,4)naphthalenophane and [6](1,4)anthracenophane with electrophiles

Tobe, Yoshito, Takemura, Akihiro, Jimbo, Mamoru, Takahashi, Tohru, Kobiro, Kazuya, Kakiuchi, Kiyomi

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 2.42 MB

english, 1992

23

Determination of conformation and relative configuration of a small, rapidly tumbling molecule in solution by combined application of NOESY and restrained MD calculations

Reggelin, Michael, Hoffmann, Holger, Koeck, Matthias, Mierke, Dale F.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 752 KB

english, 1992

24

Intrasubstituent isotope effect studies of oxidative N-demethylations catalyzed by secondary amine monooxygenase. Comparison to cytochrome P-450

Hawkins, Barton K., Dawson, John H.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 419 KB

english, 1992

25

Structural effects in the recognition of DNA by circular oligonucleotides

Prakash, Gautam, Kool, Eric T.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1020 KB

english, 1992

26

Book Review

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 687 KB

english, 1992

27

Mechanism of halide-induced disproportionation of M(CO)3(PCy3)2+ 17-electron radicals (M = iron, ruthenium, osmium). Periodic trends on reactivity and the role of ion pairs

Song, Lin, Trogler, William C.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 893 KB

english, 1992

28

An alternative preparation of organofunctionalized silica gels and their characterization by two-dimensional high-resolution solid-state heteronuclear NMR correlation spectroscopy

Fyfe, C. A., Zhang, Y., Aroca, P.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 458 KB

english, 1992

29

Experimental evaluation of transition structure geometry for an aryl bromide-alkyllithium exchange reaction: new information relevant to the reaction mechanism

Beak, Peter, Allen, David J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 769 KB

english, 1992

30

Photoisomerization of polyenes. 30. Quantum chain processes in photoisomerization of the all-trans, 7-cis, and 11-cis isomers of retinal.

Ganapathy, Srinivasan, Liu, Robert S. H.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 750 KB

english, 1992

31

Reaction of (E)-O-arylbenzaldoximes with sodium methoxide in methanol. Effect of leaving group upon nitrile-forming transition state

Cho, Bong Rae, Jung, Jinhee, Ahn, Eun Kyung

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 717 KB

english, 1992

32

A molecular merry-go-round: motion of the large macrocyclic molecule 18-crown-6 in its solid complexes studied by deuterium NMR

Ratcliffe, C. I., Ripmeester, J. A., Buchanan, G. W., Denike, J. K.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 707 KB

english, 1992

33

Carbon-13-carbon-13 spin coupling constants in aldoses enriched with 13C at the terminal hydroxymethyl carbon: effect of coupling pathway structure of JCC in carbohydrates.

Wu, Jian, Bondo, Paul B., Vuorinen, Tapani, Serianni, Anthony S.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 916 KB

english, 1992

34

Free energy profiles for sodium cation adsorption on a metal electrode

Matsui, Tooru, Jorgensen, William L.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.63 MB

english, 1992

35

Determination of absolute stereochemistry of acyclic 1,3-polyols by a difference CD method

Mori, Yuji, Kohchi, Yasunori, Suzuki, Makoto, Furukawa, Hiroshi

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 436 KB

english, 1992

36

Electrospray mass spectrometry of poly(ethylene glycols) with molecular weights up to five million

Nohmi, Takashi, Fenn, John B.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 793 KB

english, 1992

37

High-spin chemical bonding of metal monocarbonothioyl and -carbonyl [MCS and MCO] (M = Sc, Ti, V, Cr, Cu)

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 440 KB

english, 1992

38

W6(H)5(O-Pr-iso)13. A polynuclear-polyhydride tungsten complex supported exclusively by alkoxide ligands

Chisholm, Malcolm H., Kramer, Keith S., Streib, William E.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 411 KB

english, 1992

39

Claisen rearrangement of allyl phenyl ether. 1-carbon-14 and .beta.-carbon-14 kinetic isotope effects. A clearer view of the transition structure

Kupczyk-Subotkowska, Lidia, Subotkowski, Witold, Saunders, William H., Shine, Henry J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 662 KB

english, 1992

40

Use of NMR spectroscopy to determine bond orders between .beta.- and .beta.'-pyrrolic positions of porphyrins: structural differences between free-base porphyrins and metalloporphyrins

Crossley, Maxwell J., Harding, Margaret M., Sternhell, Sever

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 905 KB

english, 1992

41

Formation of fibrous molecular assemblies by amino acid surfactants in water

Imae, Toyoko, Takahashi, Yoshiyuki, Muramatsu, Hidetoshi

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.93 MB

english, 1992

42

Hydrogen-bonded oxyhemoglobin models with substituted picket-fence porphyrins: the model compound equivalent of site-directed mutagenesis

Wuenschell, Gerald E., Tetreau, Catherine, Lavalette, Daniel, Reed, Christopher A.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.67 MB

english, 1992

43

Developing magnetic and metallic behavior in high-nuclearity nickel cluster carbonyls. A LCGTO-LDF study of [Ni9(CO)18]n-, [Ni10Ge(CO)20]n-, [Ni32C6(CO)36]n-, and [Ni44(CO)48]n- compounds

Roesch, Notker, Ackermann, Lutz, Pacchioni, Gianfranco

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.15 MB

english, 1992

44

Inhibition of 5-enolpyruvoylshikimate 3-phosphate (EPSP) synthase by analogs of the tetrahedral intermediate and of EPSP

Alberg, David G., Lauhon, Charles T., Nyfeler, Robert, Faessler, Alex, Bartlett, Paul A.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.76 MB

english, 1992

45

The interaction of biological molecules with heparin and related glycosaminoglycans. 1. Identification of a specific heparin binding site for histamine

Rabenstein, Dallas L., Bratt, Peter, Schierling, Timothy D., Robert, Jan M., Guo, Wei

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 991 KB

english, 1992

46

Identification of the iron ions of high potential iron protein from Chromatium vinosum within the protein frame through two-dimensional NMR experiments

Bertini, Ivano, Capozzi, Francesco, Ciurli, Stefano, Luchinat, Claudio, Messori, Luigi, Piccioli, Mario

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.07 MB

english, 1992

47

Antigenic peptide binding to the mouse major histocompatibility complex class II protein I-Ek. Peptide stabilization of the quarternary structure of I-Ek

Witt, Stephan N., McConnell, Harden M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.07 MB

english, 1992

48

Polyoxo alkoxides of vanadium: the structures of the decanuclear vanadium(IV) clusters [V10O16{CH3CH2C(CH2O)3}4]4- and [V10O13{CH3CH2C(CH2O)3}5]-

Khan, M. Ishaque, Chen, Qin, Goshorn, D. P., Hope, Hakon, Parkin, Sean, Zubieta, Jon

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 663 KB

english, 1992

49

Substituent effects of an antibody-catalyzed hydrolysis of phenyl esters: further evidence for an acyl-antibody intermediate

Gibbs, Richard A., Benkovic, Patricia A., Janda, Kim D., Lerner, Richard A., Benkovic, Stephen J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 906 KB

english, 1992

50

Efficient photosensitized pyrimidine dimer splitting by a reduced flavin requires the deprotonated flavin

Hartman, Rosemarie F., Rose, Seth D.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 308 KB

english, 1992

51

Formation and reactions of mono- and bis(peralkylcyclopentadienyl) complexes of calcium and barium. The x-ray crystal structure of [cyclic][(Me4EtC5)Ca(.mu.-NSiMe2CH2CH2SiMe2)]2

Sockwell, S. Craig, Hanusa, Timothy P., Huffman, John C.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.00 MB

english, 1992

52

A conformational study of peptides with the general structure Ac-L-Xaa-Pro-D-Xaa-L-Xaa-NH2: spectroscopic evidence for a peptide with significant .beta.-turn character in water and in dimethyl sulfoxide

Imperiali, B., Moats, R. A., Fisher, S. L., Prins, T. J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 862 KB

english, 1992

53

Time-resolved UV resonance Raman study on Bohr effects of hemoglobin

Kaminaka, Shoji, Kitagawa, Teizo

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 604 KB

english, 1992

54

Aldehyde ferredoxin oxidoreductase from the hyperthermophilic archaebacterium Pyrococcus furiosus contains a tungsten oxo-thiolate center

George, Graham N., Prince, Roger C., Mukund, Swarnalatha, Adams, Michael W. W.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 384 KB

english, 1992

55

Conformation-controlled hydrolysis of polyribonucleotides by sequential basic polypeptides

Barbier, Bernard, Brack, Andre

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 516 KB

english, 1992

56

Structural characterization of zinc(II) complexes of octaethyloxophlorin dianion and octaethyloxophlorin radical anion

Balch, Alan L., Noll, Bruce C., Zovinka, Edward P.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 745 KB

english, 1992

57

Ion pickup of large, surface-adsorbed molecules: a demonstration of the Eley-Rideal mechanism

Williams, E. R., Jones, G. C., Fang, L., Zare, R. N., Garrison, B. J., Brenner, D. W.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.03 MB

english, 1992

58

Role of solvent dynamics in the charge recombination of a donor/acceptor pair

Zaleski, Jeffrey M., Chang, Chi K., Leroi, George E., Cukier, Robert I., Nocera, Daniel G.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 295 KB

english, 1992

59

Reversible cleavage of chromium-chromium quadruple bond of [Me8Cr2][Li(THF)]4 via modification of the coordination sphere of the alkali cation. Preparation and crystal structure of monomeric [Me4Cr][Li(TMEDA)]2

Hao, Shoukang, Gambarotta, Sandro, Bensimon, Corinne

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 304 KB

english, 1992

60

Masthead

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 159 KB

english, 1992

61

Materials chemistry of chiral macromolecules. 1. Synthesis and phase transitions

Moore, J. S., Stupp, S. I.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 2.17 MB

english, 1992

62

Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations

Murthy, Srihari, Nagano, Yatsuhisa, Beauchamp, J. L.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 277 KB

english, 1992

63

Mechanistic studies of enzymic and nonenzymic prolyl cis-trans isomerization

Harrison, Richard K., Stein, Ross L.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.00 MB

english, 1992

64

Sequential site-directed mutagenesis and chemical modification to convert the active site arginine 292 of aspartate aminotransferase to homoarginine

White, Peter W., Kirsch, Jack F.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 308 KB

english, 1992

65

Photoinduced electron transfer from zinc cytochrome c to plastocyanin is gated by surface diffusion within the metalloprotein complex

Zhou, Jian S., Kostic, Nenad M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 281 KB

english, 1992

66

Highly chemo- and stereoselective cyclopolymerization of 2-methyl-1,5-hexadiene: chain transfer via .beta.-CH3 elimination

Kesti, Michael R., Waymouth, Robert M.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 442 KB

english, 1992

67

Computer Software Reviews

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 347 KB

english, 1992

68

A new definition of functional groups and a general procedure for their identification in organic structures

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 748 KB

english, 1992

69

Physicochemical properties of (R)- vs (S)-methylphosphonate substitution on antisense DNA hybridization determined by free energy perturbation and molecular dynamics

Hausheer, F. H., Rao, B. G., Saxe, J. D., Singh, U. C.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 2.39 MB

english, 1992

70

Stereospecific synthesis of aryl .beta.-glucosides: an application to the synthesis of a prototype corresponding to the aryloxy carbohydrate domain of vancomycin

Dushin, Russell G., Danishefsky, Samuel J.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 741 KB

english, 1992

71

Total synthesis and absolute stereochemical assignment of gilvocarcin M.

Matsumoto, Takashi, Hosoya, Takamitsu, Suzuki, Keisuke

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 420 KB

english, 1992

72

The redesign of a type 2 into a type 1 copper protein: construction and characterization of yeast copper, zinc superoxide dismutase mutants

Lu, Yi, Gralla, Edith B., Roe, James A., Valentine, Joan Selverstone

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 409 KB

english, 1992

73

Rearrangement of nascent .alpha.-silyl-substituted carbenium ions in the gas phase. 1,2-Hydrogen versus 1,2-methyl versus 1,2-phenyl migration

Bakhtiar, R., Holznagel, C. M., Jacobson, D. B.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.08 MB

english, 1992

74

A combined iterative and boundary-element approach for solution of the nonlinear Poisson-Boltzmann equation

Vorobjev, Y. N., Grant, J. A., Scheraga, H. A.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 1.03 MB

english, 1992

75

An unusually rapid intramolecular general-base catalysis. Relevance to enzymology

Menger, F. M., Gabrielson, K.

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 289 KB

english, 1992