Volume 125; Issue 31

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Journal of the American Chemical Society
Volume 125; Issue 31

Journal of the American Chemical Society

Volume 125; Issue 31

1

Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing

Okamoto, Akimitsu, Tanaka, Kazuo, Fukuta, Tetsuo, Saito, Isao

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 102 KB

english, 2003

2

Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance

Zhang, Yun, Telyatnikov, Vladislav, Sathe, Megahna, Zeng, Xiangqun, Wang, Peng George

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 109 KB

english, 2003

3

Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions

McComas, Casey C., Crowley, Brendan M., Boger, Dale L.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 62 KB

english, 2003

4

Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds

Lalevée, Jacques, Allonas, Xavier, Genet, Sébastien, Fouassier, Jean-Pierre

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 62 KB

english, 2003

5

3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration

Gao, Xuri, Hall, Dennis G.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 54 KB

english, 2003

6

Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets

Chen, Wei, Yuan, Hong-Ming, Wang, Jia-Yu, Liu, Zhao-Yue, Xu, Jin-Jie, Yang, Min, Chen, Jie-Sheng

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 102 KB

english, 2003

7

On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy

Levy, Ronald M., Zhang, Linda Y., Gallicchio, Emilio, Felts, Anthony K.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 115 KB

english, 2003

8

[3+3]Cycloalkyne Dimers Linked by an Azo Group: A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions

Saiki, Yuto, Sugiura, Hiroki, Nakamura, Keiichi, Yamaguchi, Masahiko, Hoshi, Tomonori, Anzai, Jun-ichi

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 185 KB

english, 2003

9

An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids

Audic, Nicolas, Clavier, Hervé, Mauduit, Marc, Guillemin, Jean-Claude

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 52 KB

english, 2003

10

Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile

Handoo, Kishan L., Lu, Yun, Parker, Vernon D.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 104 KB

english, 2003

11

A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins: Application to E. coli Ribonuclease H1

Babu, C. Satheesan, Dudev, Todor, Casareno, R., Cowan, J. A., Lim, Carmay

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 473 KB

english, 2003

12

Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate

Arimoto, Yoichi, Ohkoshi, Shin-ichi, Zhong, Zhuang Jin, Seino, Hidetake, Mizobe, Yasushi, Hashimoto, Kazuhito

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 76 KB

english, 2003

13

Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density

Herrwerth, Sascha, Eck, Wolfgang, Reinhardt, Sven, Grunze, Michael

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 198 KB

english, 2003

14

Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines

Jaska, Cory A., Temple, Karen, Lough, Alan J., Manners, Ian

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 346 KB

english, 2003

15

Study of the Chemistry of o rtho - and p ara -Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations

Tsao, Meng-Lin, Gritsan, Nina, James, Tammi R., Platz, Matthew S., Hrovat, David A., Borden, Weston Thatcher

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 573 KB

english, 2003

16

Tin-Centered Radical and Cation: Stable and Free

Sekiguchi, Akira, Fukawa, Tomohide, Lee, Vladimir Ya., Nakamoto, Masaaki

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 53 KB

english, 2003

17

Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials

Dufaud, Véronique, Davis, Mark E.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 233 KB

english, 2003

18

First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes

Fave, Claire, Cho, Ting-Yi, Hissler, Muriel, Chen, Chieh-Wei, Luh, Tien-Yau, Wu, Chung-Chih, Réau, Régis

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 66 KB

english, 2003

19

Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers

Gaab, Kevin M., Thompson, Alexis L., Xu, Jianjun, Martínez, Todd J., Bardeen, Christopher J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 48 KB

english, 2003

20

Chemistry and Applications of Polyphosphazenes By Harry R. Allcock (The Pennsylvania State University). John Wiley & Sons, Inc.: Hoboken. 2003. xii + 726 pp. $325.00. ISBN 0-471-44371-9.

Neilson, Robert H.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 17 KB

english, 2003

21

A Heterocyclic Peptide Nanotube

Horne, W. Seth, Stout, C. David, Ghadiri, M. Reza

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 200 KB

english, 2003

22

Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites

Viswanathan, Gunaranjan, Chakrapani, Nirupama, Yang, Hoichang, Wei, Bingqing, Chung, Hyunsoo, Cho, Kilwon, Ryu, Chang Y., Ajayan, Pulickel M.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 124 KB

english, 2003

23

The Role of the HOOO - Anion in the Ozonation of Alcohols: Large Differences in the Gas-Phase and in the Solution-Phase Mechanism

Wu, Anan, Cremer, Dieter, Plesničar, Božo

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 189 KB

english, 2003

24

Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum n igrum

Bell, Phillip J. L., Karuso, Peter

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 299 KB

english, 2003

25

Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC 4 M‘] n + : Computational Analyses of the Effect of the Metal

Jiao, Haijun, Costuas, Karine, Gladysz, John A., Halet, Jean-François, Guillemot, Maud, Toupet, Loic, Paul, Frédéric, Lapinte, Claude

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 260 KB

english, 2003

26

“Belt and Braces”: A Peptide-Based Linker System of de Novo Design

Ryadnov, Maxim G., Ceyhan, Buelent, Niemeyer, Christof M., Woolfson, Derek N.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 200 KB

english, 2003

27

Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures

Lou, Zhengsong, Chen, Qianwang, Zhang, Yufeng, Wang, Wei, Qian, Yitai

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 70 KB

english, 2003

28

Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts

Stapleton, Russell A., Galan, Brandon R., Collins, Scott, Simons, Richard S., Garrison, Jered C., Youngs, Wiley J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 58 KB

english, 2003

29

Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?

Crumpton-Bregel, Dawn M., Goldberg, Karen I.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 231 KB

english, 2003

30

Electronic Excitation Energies of Zn i O i Clusters

Matxain, Jon M., Mercero, Jose M., Fowler, Joseph E., Ugalde, Jesus M.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 216 KB

english, 2003

31

Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas-Phase Dissociation and Reactivity

Zhang, Haizhen, Paulsen, Eric S., Walker, Kevin A., Krakowiak, Krzysztof E., Dearden, David V.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 75 KB

english, 2003

32

Stereospecific Photochemical Ring Expansion of Lithiated Benzamides

Clayden, Jonathan, Knowles, Faye E., Menet, Christel J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 85 KB

english, 2003

33

Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements

Mushrush, Melissa, Facchetti, Antonio, Lefenfeld, Michael, Katz, Howard E., Marks, Tobin J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 213 KB

english, 2003

34

Total Synthesis of Elisabethin A: Intramolecular Diels−Alder Reaction under Biomimetic Conditions [ J. Am. Chem. Soc . 2003 , 125 , 4680−4681].

Heckrodt, Thilo J., Mulzer, Johann

Journal:

Journal of the American Chemical Society

Year:

2003

File:

PDF, 18 KB

2003

35

Φ-Values beyond the Ribosomally Encoded Amino Acids: Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein

Horng, Jia-Cherng, Raleigh, Daniel P.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 56 KB

english, 2003

36

Cationic Assembly of Metal Complex Aggregates: Structural Diversity, Solution Stability, and Magnetic Properties

Lin, Xiang, Doble, Dan M. J., Blake, Alexander J., Harrison, Andrew, Wilson, Claire, Schröder, Martin

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 428 KB

english, 2003

37

Mutasynthesis of Enterocin and Wailupemycin Analogues

Kalaitzis, John A., Izumikawa, Miho, Xiang, Longkuan, Hertweck, Christian, Moore, Bradley S.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 54 KB

english, 2003

38

First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures

Huang, Feihe, Gibson, Harry W., Bryant, William S., Nagvekar, Devdatt S., Fronczek, Frank R.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 222 KB

english, 2003

39

Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements

Iwamoto, Takeaki, Masuda, Hidenori, Ishida, Shintaro, Kabuto, Chizuko, Kira, Mitsuo

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 57 KB

english, 2003

40

Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2)

Hossain, Md. Zakir, Machida, Shin-ichi, Yamashita, Yoshiyuki, Mukai, Kozo, Yoshinobu, Jun

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 83 KB

english, 2003

41

Structure and Phase Transitions of Alkyl Chains on Mica

Heinz, Hendrik, Castelijns, Hein J., Suter, Ulrich W.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 856 KB

english, 2003

42

A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene

Kon, Yoshihiro, Ogasawara, Jun, Sakamoto, Kenkichi, Kabuto, Chizuko, Kira, Mitsuo

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 60 KB

english, 2003

43

A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond: Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide

Datta, Swarup, Chang, Chia-Lung, Yeh, Kuo-Liang, Liu, Rai-Shung

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 69 KB

english, 2003

44

Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide

Goddard, Jean-Philippe, Lixon, Patricia, Le Gall, Thierry, Mioskowski, Charles

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 53 KB

english, 2003

45

A Cationic Guest in a 24 + Cationic Host

Bourgeois, Jean-Pascal, Fujita, Makoto, Kawano, Masaki, Sakamoto, Shigeru, Yamaguchi, Kentaro

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 85 KB

english, 2003

46

Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer

Zhang, Jie, Barker, Anna L., Mandler, Daniel, Unwin, Patrick R.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 52 KB

english, 2003

47

A New Class of Modular Chiral Ligands with Fluxional Groups

Sibi, Mukund P., Zhang, Ruzhou, Manyem, Shankar

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 58 KB

english, 2003

48

Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View through the Prism of Marcus Theory

Alabugin, Igor V., Manoharan, Mariappan, Breiner, Boris, Lewis, Frederick D.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 658 KB

english, 2003

49

α- and β-A 2 Hg 3 M 2 S 8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response

Liao, J.-H., Marking, G. M., Hsu, K. F., Matsushita, Y., Ewbank, M. D., Borwick, R., Cunningham, P., Rosker, M. J., Kanatzidis, M. G.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 463 KB

english, 2003

50

Influence of Delocalization on the Stability of Dianions: Study of a Systematic Series of Dianions with Growing Electronic Localization

Feuerbacher, Sven, Cederbaum, Lorenz S.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 120 KB

english, 2003

51

Self-Assembled Nanostructures By Jin Z. Zhang (University of California, Santa Cruz), Zhong-Lin Wang (Georgia Institute of Technology), Jun Liu (Sandia National Labs), Shaowei Chen (Southern Illinois University), and Gang-Yu Liu (University of California, Davis). Kluwer Academic/Plenum Publisher: New York. 2003. xviii + 316 pp. $135.00. ISBN 0-306-47299-6.

Vanden Bout, David A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 17 KB

english, 2003

52

Biocatalysis in Polymer Science Edited by Richard A. Gross (Polytechnic University) and H. N. Cheng (Hercules Incorporated Research Center). American Chemical Society (Distributed by Oxford University Press): Washington, DC. 2003. xvi + 336 pp. $145.00. ISBN 0-8412-3781-6.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 17 KB

english, 2003

53

Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes: A Rapid, Practical Approach to Bicyclo[3.3.0]octenes

Delgado, Alejandro, Rodríguez, J. Ramón, Castedo, Luis, Mascareñas, José L.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 47 KB

english, 2003

54

Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds

Sadow, Aaron D., Tilley, T. Don

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 306 KB

english, 2003

55

Handbook of Molecular Physics and Quantum Chemistry, Volumes 1−3 Edited by Stephen Wilson (Rutherford Appleton Laboratory, Chilton, U.K.), Peter F. Bernath (University of Waterloo, Ontario, Canada), and Roy McWeeny (Università di Pisa, Italy). John Wiley & Sons, Ltd: Chichester. 2003. 2200 pp. $895.00. ISBN 0-471-62374-1.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 17 KB

english, 2003

56

Quantitative Measure for the “Nakedness” of Fluoride Ion Sources

Christe, Karl O., Jenkins, H. Donald Brooke

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 169 KB

english, 2003

57

TNA Synthesis by DNA Polymerases

Chaput, John C., Szostak, Jack W.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 54 KB

english, 2003

58

A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation

Huang, Feihe, Fronczek, Frank R., Gibson, Harry W.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 79 KB

english, 2003

59

The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers

Konno, Takumi, Haneishi, Kazuyuki, Hirotsu, Masakazu, Yamaguchi, Tadashi, Ito, Tasuku, Yoshimura, Takashi

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 80 KB

english, 2003

60

Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation: Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex

Stephens, Frances H., Figueroa, Joshua S., Diaconescu, Paula L., Cummins, Christopher C.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 58 KB

english, 2003

61

Stereoelectronic Effects on Collagen Stability: The Dichotomy of 4-Fluoroproline Diastereomers

Hodges, Jonathan A., Raines, Ronald T.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 73 KB

english, 2003

62

Effect of Catenation on Protein Folding Stability

Zhou, Huan-Xiang

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 53 KB

english, 2003

63

Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex

Blue, Elizabeth D., Davis, Amelia, Conner, David, Gunnoe, T. Brent, Boyle, Paul D., White, P. S.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 148 KB

english, 2003

64

Formation of Nanostructured Polymer Filaments in Nanochannels

Peng, Chih-Yi, Nam, Wook Jun, Fonash, Stephen J., Gu, Bin, Sen, Ayusman, Strawhecker, Kenneth, Natarajan, Sudarshan, Foley, Henry C., Kim, Seong H.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 266 KB

english, 2003

65

Solventless Polymerization: Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels

Gu, Hongwei, Xu, Chenjie, Weng, Lu-Tao, Xu, Bing

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 251 KB

english, 2003

66

Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process

Dias, H. V. Rasika, Browning, R. Greg, Polach, Sharon A., Diyabalanage, Himashinie V. K., Lovely, Carl J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 50 KB

english, 2003

67

Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper

Bramlett, Matthew R., Tan, Xiangshi, Lindahl, Paul A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 42 KB

english, 2003

68

Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans

Trost, Barry M., Shen, Hong C., Dong, Li, Surivet, Jean-Philippe

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 55 KB

english, 2003