Volume 125; Issue 8

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Journal of the American Chemical Society
Volume 125; Issue 8

Journal of the American Chemical Society

Volume 125; Issue 8

1

Efficient Synthesis of NK1 Receptor Antagonist Aprepitant Using a Crystallization-Induced Diastereoselective Transformation†

Brands, Karel M. J., Payack, Joseph F., Rosen, Jonathan D., Nelson, Todd D., Candelario, Alexander, Huffman, Mark A., Zhao, Matthew M., Li, Jing, Craig, Bridgette, Song, Zhiguo J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 138 KB

english, 2003

2

Barium Azacryptand Sodide, the First Alkalide with an Alkaline Earth Cation, Also Contains a Novel Dimer, (Na2)2-

Redko, Mikhail Y., Huang, Rui H., Jackson, James E., Harrison, James F., Dye, James L.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 134 KB

english, 2003

3

Induced Alignment of a Solution-Cast Discotic Hexabenzocoronene Derivative for Electronic Devices Investigated by Surface X-ray Diffraction

Bunk, Oliver, Nielsen, Martin M., Sølling, Theis I., van de Craats, Anick M., Stutzmann, Natalie

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 138 KB

english, 2003

4

Reaction Pathways of the Simmons−Smith Reaction

Nakamura, Masaharu, Hirai, Atsushi, Nakamura, Eiichi

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 303 KB

english, 2003

5

{Tl[Au(C6Cl5)2]}n: A Vapochromic Complex

Fernández, Eduardo J., López-de-Luzuriaga, José M., Monge, Miguel, Olmos, M. Elena, Pérez, Javier, Laguna, Antonio, Mohamed, Ahmed A., Fackler, John P.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 111 KB

english, 2003

6

Are the Enolates of Amides and Esters Stabilized by Electrostatics?

Rablen, Paul R., Bentrup, Keith H.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 82 KB

english, 2003

7

Zeolite-Confined Nano-RuO 2 : A Green, Selective, and Efficient Catalyst for Aerobic Alcohol Oxidation

Zhan, Bi-Zeng, White, Mary Anne, Sham, Tsun-Kong, Pincock, James A., Doucet, René J., Rao, K. V. Ramana, Robertson, Katherine N., Cameron, T. Stanley

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 148 KB

english, 2003

8

Mechanism of a Chemical Classic: Quantum Chemical Investigation of the Autocatalyzed Reaction of the Serendipitous Wöhler Synthesis of Urea

Tsipis, Constantinos A., Karipidis, Paraskevas A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 596 KB

english, 2003

9

Mechanism of Charging and Supercharging Molecules in Electrospray Ionization

Iavarone, Anthony T., Williams, Evan R.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 182 KB

english, 2003

10

DNA−Dye Conjugates for Controllable H* Aggregation 1

Asanuma, Hiroyuki, Shirasuka, Kenji, Takarada, Tohru, Kashida, Hiromu, Komiyama, Makoto

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 183 KB

english, 2003

11

Self-Assembly of Spherical Colloids into Helical Chains with Well-Controlled Handedness

Yin, Yadong, Xia, Younan

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 145 KB

english, 2003

12

A Highly Reduced V 23+ Unit with a Metal−Metal Bond Order of 3.5

Cotton, F. Albert, Hillard, Elizabeth A., Murillo, Carlos A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 51 KB

english, 2003

13

Reactivity of Substituted Charged Phenyl Radicals toward Components of Nucleic Acids

Ramírez-Arizmendi, Luis E., Heidbrink, Jenny L., Guler, Leonard P., Kenttämaa, Hilkka I.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 199 KB

english, 2003

14

Design of Triple Helix Forming C-Glycoside Molecules

Li, Jian-Sen, Fan, Yun-Hua, Zhang, Yi, Marky, Luis A., Gold, Barry

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 453 KB

english, 2003

15

Single-Precursor, One-Pot Versatile Synthesis under near Ambient Conditions of Tunable, Single and Dual Band Fluorescing Metal Sulfide Nanoparticles

Pradhan, Narayan, Efrima, Shlomo

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 48 KB

english, 2003

16

Cryogenic CO Oxidation on TiO 2 -Supported Gold Nanoclusters Precovered with Atomic Oxygen

Kim, Tae S., Stiehl, James D., Reeves, Christopher T., Meyer, Randall J., Mullins, C. Buddie

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 41 KB

english, 2003

17

Functionalized Boron Nitride Nanotubes with a Stannic Oxide Coating: A Novel Chemical Route to Full Coverage

Han, Wei-Qiang, Zettl, Alex

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 118 KB

english, 2003

18

Thiyl Radicals Abstract Hydrogen Atoms from the α C−H Bonds in Model Peptides: Absolute Rate Constants and Effect of Amino Acid Structure

Nauser, Thomas, Schöneich, Christian

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 58 KB

english, 2003

19

Benzylation of Aromatic Compounds with Different Crystallites of MgO

Choudary, Boyapati M., Mulukutla, Ravichandra S., Klabunde, Kenneth J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 86 KB

english, 2003

20

The Bis-Barium Complex of a Butterfly Crown Ether as a Phototunable Supramolecular Catalyst

Cacciapaglia, Roberta, Di Stefano, Stefano, Mandolini, Luigi

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 140 KB

english, 2003

21

Electrochemical Infrared Characterization of CO Domains on Ruthenium-Decorated Platinum Nanoparticles

Park, Sungho, Wieckowski, Andrzej, Weaver, Michael J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 214 KB

english, 2003

22

Enhancement of the ETS-10 Titanosilicate Activity in the Shape-Selective Photocatalytic Degradation of Large Aromatic Molecules by Controlled Defect Production

Llabrés i Xamena, Francesc X., Calza, Paola, Lamberti, Carlo, Prestipino, Carmelo, Damin, Alessandro, Bordiga, Silvia, Pelizzetti, Ezio, Zecchina, Adriano

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 204 KB

english, 2003

23

Modeling Random Methyl Branching in Ethylene/ Propylene Copolymers Using Metathesis Chemistry: Synthesis and Thermal Behavior

Sworen, John C., Smith, Jason A., Wagener, Kenneth B., Baugh, Lisa S., Rucker, Steven P.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 253 KB

english, 2003

24

Copper Ion-Induced Activation and Asymmetric Benzoylation of 1,2-Diols: Kinetic Chiral Molecular Recognition

Matsumura, Yoshihiro, Maki, Toshihide, Murakami, Sachie, Onomura, Osamu

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 48 KB

english, 2003

25

Novel Iminium Ion Equivalents Prepared through C−H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives

Fleming, James J., Fiori, Kristin Williams, Du Bois, J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 71 KB

english, 2003

26

Memory Effects Based on Intermolecular Photoinduced Proton Transfer

Raymo, Françisco M., Alvarado, Robert J., Giordani, Silvia, Cejas, Mabel A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 189 KB

english, 2003

27

Direct Catalytic Asymmetric Aldol Reaction of Hydroxyketones: Asymmetric Zn Catalysis with a Et 2 Zn/Linked-BINOL Complex

Kumagai, Naoya, Matsunaga, Shigeki, Kinoshita, Tomofumi, Harada, Shinji, Okada, Shigemitsu, Sakamoto, Shigeru, Yamaguchi, Kentaro, Shibasaki, Masakatsu

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 320 KB

english, 2003

28

Understanding the Correlation of Structure and Selectivity in the Chiral-Phosphoramide-Catalyzed Enantioselective Allylation Reactions: Solution and Solid-State Structural Studies of Bisphosphoramide·SnCl 4 Complexes

Denmark, Scott E., Fu, Jiping

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 359 KB

english, 2003

29

Cyclopentadienyl Substituent Effects on Reductive Elimination Reactions in Group 4 Metallocenes: Kinetics, Mechanism, and Application to Dinitrogen Activation

Pool, Jaime A., Lobkovsky, Emil, Chirik, Paul J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 314 KB

english, 2003

30

Designer Chiral Quaternary Ammonium Bifluorides as an Efficient Catalyst for Asymmetric Nitroaldol Reaction of Silyl Nitronates with Aromatic Aldehydes

Ooi, Takashi, Doda, Kanae, Maruoka, Keiji

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 45 KB

english, 2003

31

Native Conformational Tendencies in Unfolded Polypeptides: Development of a Novel Method To Assess Native Conformational Tendencies in the Reduced Forms of Multiple Disulfide-Bonded Proteins

Narayan, Mahesh, Welker, Ervin, Scheraga, Harold A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 34 KB

english, 2003

32

Asymmetric Organocatalysis of 4 + 3 Cycloaddition Reactions

Harmata, Michael, Ghosh, Sunil K., Hong, Xuechuan, Wacharasindhu, Sumrit, Kirchhoefer, Patrick

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 47 KB

english, 2003

33

A [2]Catenane Constructed around a Ru(Diimine) 32+ Complex Used as a Template

Mobian, Pierre, Kern, Jean-Marc, Sauvage, Jean-Pierre

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 65 KB

english, 2003

34

One-Electron Oxidation of the Guanine Moiety of 2‘-Deoxyguanosine: Influence of 8-Oxo-7,8-dihydro-2‘-deoxyguanosine

Ravanat, Jean-Luc, Saint-Pierre, Christine, Cadet, Jean

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 46 KB

english, 2003

35

Torsional Barriers for Planar versus Twisted Singlet Styrenes

Lewis, Frederick D., Zuo, Xiaobing

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 102 KB

english, 2003

36

Is the Ruthenium Analogue of Compound I of Cytochrome P450 an Efficient Oxidant? A Theoretical Investigation of the Methane Hydroxylation Reaction

Sharma, Pankaz K., de Visser, Sam P., Ogliaro, François, Shaik, Sason

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 217 KB

english, 2003

37

Unusual Coordination Modes of Arylthiolates in Mo{η 5 -SC 6 H 3 -2,6-(SiMe 3 ) 2 }{η 7 -SC 6 H 3 -2,6-(SiMe 3 ) 2 }

Komuro, Takashi, Matsuo, Tsukasa, Kawaguchi, Hiroyuki, Tatsumi, Kazuyuki

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 56 KB

english, 2003

38

Synthetic, Structural and Binding Studies of the 4,6-Dimethyldibenzothiophene Complex [(η 5 -C 5 Me 5 )Ru(CO) 2 (η 1 ( S )-4,6-Me 2 DBT)]BF 4 : Toward an Understanding of Deep Hydrodesulfurization

Vecchi, Paul A., Ellern, Arkady, Angelici, Robert J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 54 KB

english, 2003

39

Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 7-Octene-2,4-dione

Qian, Hua, Widenhoefer, Ross A.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 59 KB

english, 2003

40

Active-Site Structure and Electron-Transfer Reactivity of Plastocyanins

Sato, Katsuko, Kohzuma, Takamitsu, Dennison, Christopher

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 228 KB

english, 2003

41

Synthesis of 1,2-Diheteroatom-Substituted Alkenes via Rhodium-Catalyzed Intramolecular Hydrogen Transfer

Diaz-Requejo, M. Mar, DiSalvo, Darren, Brookhart, Maurice

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 53 KB

english, 2003

42

Thermodynamic Coupling of the Loop and Stem in Unusually Stable DNA Hairpins Closed by CG Base Pairs

Moody, Ellen M., Bevilacqua, Philip C.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 41 KB

english, 2003

43

Group 4 Octahedral Benzamidinate Complexes: Syntheses, Structures, and Catalytic Activities in the Polymerization of Propylene Modulated by Pressure

Volkis, Victoria, Nelkenbaum, Elza, Lisovskii, Anatoli, Hasson, Gil, Semiat, Rafi, Kapon, Moshe, Botoshansky, Mark, Eishen, Yoav, Eisen, Moris S.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 409 KB

english, 2003

44

Shishijimicins A−C, Novel Enediyne Antitumor Antibiotics from the Ascidian Didemnum proliferum 1

Oku, Naoya, Matsunaga, Shigeki, Fusetani, Nobuhiro

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 50 KB

english, 2003

45

Bonding of Atomic Phosphorus to Polycyclic Hydrocarbons and Curved Graphitic Surfaces

Melchor, Santiago, Dobado, Jose A., Larsson, J. Andreas, Greer, James C.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 193 KB

english, 2003

46

Binding and Activation of Aromatic Molecules by a Molybdenum π-Base

Meiere, Scott H., Keane, Joseph M., Gunnoe, T. Brent, Sabat, Michal, Harman, W. Dean

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 87 KB

english, 2003

47

Synthesis of Stable Derivatives of C 62 : The First Nonclassical Fullerene Incorporating a Four-Membered Ring

Qian, Wenyuan, Chuang, Shih-Ching, Amador, Roberto B., Jarrosson, Thibaut, Sander, Michael, Pieniazek, Susan, Khan, Saeed I., Rubin, Yves

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 151 KB

english, 2003

48

Mechanically Linked Polycarbonate

Fustin, Charles-André, Bailly, Christian, Clarkson, Guy J., De Groote, Philippe, Galow, Trent H., Leigh, David A., Robertson, Duncan, Slawin, Alexandra M. Z., Wong, Jenny K. Y.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 276 KB

english, 2003

49

Intercalation of Trioxatriangulenium Ion in DNA: Binding, Electron Transfer, X-ray Crystallography, and Electronic Structure

Reynisson, Jóhannes, Schuster, Gary B., Howerton, Sheldon B., Williams, Loren Dean, Barnett, Robert N., Cleveland, Charles L., Landman, Uzi, Harrit, Niels, Chaires, Jonathan B.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 715 KB

english, 2003

50

Norbornyl Cations of Group 14 Elements

Müller, Thomas, Bauch, Christian, Ostermeier, Markus, Bolte, Michael, Auner, Norbert

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 193 KB

english, 2003

51

Biomimetic Aryl Hydroxylation Derived from Alkyl Hydroperoxide at a Nonheme Iron Center. Evidence for an Fe IV O Oxidant

Jensen, Michael P., Lange, Steven J., Mehn, Mark P., Que, Emily L., Que, Lawrence

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 338 KB

english, 2003

52

Impact of Multiple Cation−π Interactions upon Calix[4]arene Substrate Binding and Specificity

Macias, Alba T., Norton, Joseph E., Evanseck, Jeffrey D.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 191 KB

english, 2003

53

Ring-Opening Reaction of Phosphorus-Bridged [1]Ferrocenophane via Ring Slippage from η 5 - to η 1 -Cp

Mizuta, Tsutomu, Imamura, Yuki, Miyoshi, Katsuhiko

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 60 KB

english, 2003

54

Tandem Electrostatic Effect from the First to the Third Aglycon in the Trimeric RNA Owing to the Nearest-Neighbor Interaction

Acharya, P., Acharya, S., Földesi, A., Chattopadhyaya, J.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 160 KB

english, 2003

55

Porphyrin Deposition Induced by UV Irradiation

Scolaro, Luigi Monsù, Romeo, Andrea, Castriciano, Maria Angela, De Luca, Giovanna, Patanè, Salvatore, Micali, Norberto

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 141 KB

english, 2003

56

Stable Mechanistically-Relevant Aromatic-Based Carbenium Ions in Zeolite Catalysts

Clark, Louis A., Sierka, Marek, Sauer, Joachim

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 217 KB

english, 2003

57

Direct Test of the Gaussian-Chain Model for Treating Residual Charge−Charge Interactions in the Unfolded State of Proteins

Zhou, Huan-Xiang

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 41 KB

english, 2003

58

Structural and Vibrational Study of the Tautomerism of Histamine Free-Base in Solution

Ramírez, F. Javier, Tuñón, Iñaki, Collado, Juan A., Silla, Estanislao

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 153 KB

english, 2003

59

Modulation of Substrate Binding to Naphthalene 1,2-Dioxygenase by Rieske Cluster Reduction/Oxidation

Yang, Tran-Chin, Wolfe, Matt D., Neibergall, Matthew B., Mekmouche, Yasmina, Lipscomb, John D., Hoffman, Brian M.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 46 KB

english, 2003

60

Thermochemistry of Arylselanyl Radicals and the Pertinent Ions in Acetonitrile

Holm, Allan Hjarbæk, Yusta, Laura, Carlqvist, Peter, Brinck, Tore, Daasbjerg, Kim

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 160 KB

english, 2003

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