Volume 92; Issue 23

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Journal of the American Chemical Society
Volume 92; Issue 23

Journal of the American Chemical Society

Volume 92; Issue 23

1

Kinetics, stereochemistry, and mechanism of the sodium borohydride reduction of alkyl-substituted cyclohexanones

Rickborn, Bruce., Wuesthoff, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.49 MB

english, 1970

2

Photochemistry of o-benzyloxyphenylglyoxylates. A case of favored intramolecular hydrogen abstraction via a seven-membered cyclic transition state

Pappas, Socrates P., Alexander, James E., Zehr, Robert D.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 670 KB

english, 1970

3

Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OET)3]4+. III. Proton nuclear magnetic resonance study of reactions with dienes

Tolman, Chadwick A.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 667 KB

english, 1970

4

Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OEt)3]4+. II. Reaction with 1,3-butadiene. Catalytic formation of hexadienes

Tolman, Chadwick A.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.02 MB

english, 1970

5

Tris[3-(tert-butylhydroxymethylene)-d-camphorato]europium(III). A reagent for determining enantiomeric purity

Whitesides, George M., Lewis, Daniel William.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 259 KB

english, 1970

6

Infrared intensities as a quantitative measure of intramolecular interactions. XV. Monosubstituted ethylenes

Katritzky, Alan R., Pinzelli, R. F., Sinnott, M. V., Topsom, R. D.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 692 KB

english, 1970

7

Preparation and fragmentation of the 3-thiabicyclo[3.1.0]hexane 3,3-dioxide ring system. Synthesis of 1,4-dienes

Mock, William L.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.12 MB

english, 1970

8

Mechanism of the base-catalyzed interconversion of .gamma.-diketones

Yates, Peter., Betts, Michael J.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 275 KB

english, 1970

9

Perfluorophenylsilver

Miller, William Taylor., Sun, Kwok K.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 388 KB

english, 1970

10

Additions to bicyclic olefins. III. Stereochemistry of the epoxidation of norbornene, 7,7-dimethylnorbornene, and related bicyclic olefins. Steric effects in the 7,7-dimethylnorbornyl system

Brown, Herbert Charles., Kawakami, James H., Ikegami, Shiro.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 491 KB

english, 1970

11

Origin of carbon 1 in tetrahydroisoquinoline alkaloids

Kapadia, Govind J., Rao, G. Subba., Leete, Edward., Fayez, M. B. E., Vaishnav, Y. N., Fales, Henry M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.03 MB

english, 1970

12

Substituent effects in unimolecular ion decompositions. XV. Mechanistic interpretations and the quasi-equilibrium theory

McLafferty, Fred W., Wachs, Timothy., Lifshitz, Chava., Innorta, Giuseppe., Irving, Philip.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.58 MB

english, 1970

13

Structural characterization of tris(N,N-di-n-butyldithiocarbamato)nickel(IV) bromide. A Ni-S6 complex with unusual chemical properties

Fackler, John P., Avdeef, Alex., Fischer, Robert G.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 363 KB

english, 1970

14

Selective cyanylation of sulfhydryl groups

Patchornik, Abraham., Degani, Y., Neumann, Hava.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 358 KB

english, 1970

15

Mechanisms of elimination reactions. XVII. Relation between stereochemistry and trans:cis ratios in eliminations from open-chain quaternary ammonium salts

Saunders, William H., Bailey, David Scott., Montgomery, Fredrick C., Chodak, Gerald W.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 363 KB

english, 1970

16

Electrical effect of free-radical groups

Jaffe, Hans H., Billets, Stephen.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 124 KB

english, 1970

17

Effect of 4,4-dideuteration of nicotinamide adenine dinucleotide phosphate on steroid hydroxylation

Holtzman, Jordan L.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 251 KB

english, 1970

18

Rapid intramolecular rearrangements in pentacoordinate transition metal compounds. Rearrangement mechanism of some fluxional iridium(I) complexes

Osborn, John A., Shapley, John R.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 363 KB

english, 1970

19

Skeletal rearrangements of 2-pyrones involving 1,5-sigmatropic hydrogen shifts

Pirkle, William H., Seto, Herbert G., Turner, Walter V.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 266 KB

english, 1970

20

Magnetic resonance measurements of proton exchange in aqueous urea

Vold, Robert L., Daniel, E. S., Chan, S. O.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 669 KB

english, 1970

21

Acid-base reactions of N, N, N', N'-tetramethyl-p-phenylenediamine with carboxylic acids in benzene at 25.deg.

Steigman, Joseph., Cronkright, Walter.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 817 KB

english, 1970

22

Mechanisms of elimination reactions. XVI. Stereochemistry of elimination from 2- and 3-hexyltrimethylammonium ions. An explanation of the syn-anti dichotomy

Saunders, William H., Bailey, David Scott.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 972 KB

english, 1970

23

Nybomycin. III. Revised structure

Rinehart, Kenneth L., Leadbetter, Graham., Larson, Richard A., Forbis, Richard M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 266 KB

english, 1970

24

Photochemical reaction of bis(1,3-diketonato)nickel(II) chelates

Lintvedt, Richard L., Gafney, Harry D.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 263 KB

english, 1970

25

Rearrangements of molecular ions of dialkyl-N-nitrosamines

Jaffe, Hans H., Billets, Stephen., Kaplan, Fred.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 241 KB

english, 1970

26

Mechanisms of photochemical reactions in solution. LXV. Quenching of excited singlet states of electron-rich aromatic compounds by methyl chloroacetate

Hammond, George S., McCall, M. T., Yonemitsu, Osamu., Witkop, Bernhard.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 379 KB

english, 1970

27

Exchange of olefins with oxymercurials

Halpern, Jack., Byrd, James E.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 342 KB

english, 1970

28

Electron paramagnetic resonance study of some metal ions in guanidinium aluminum sulfate hexahydrate

Carlin, Richard L., Schwartz, Robert W.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1008 KB

english, 1970

29

Nature and effect of solute-solvent interactions on vibrational spectra of rotational isomers

Woodward, A. J., El Bermani, M. F., Jonathan, Neville.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 577 KB

english, 1970

30

Flash photolytic, isotope tracer, and chemical scavenging studies of the ultraviolet photochemistry of pentaamminecobalt(III) chloride. Evidence for excited-state intermediates

Endicott, John F., Caspari, Gunter., Hughes, R. Graham., Hoffman, Morton Z.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.23 MB

english, 1970

31

Kinetic and thermodynamic studies of acetals and ketals in the naphthalene series

Newman, Melvin S., Dickson, Robert E.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 608 KB

english, 1970

32

Rotational barriers in 1-propyl cations

Pople, John A., Schleyer, Paul v. R., Radom, Leo., Buss, Volker.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 237 KB

english, 1970

33

Triarylboron anion radicals and the reductive cleavage of boron compounds

Leffler, John E., Watts, G. B., Tanigaki, T., Dolan, E., Miller, Daniel S.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 650 KB

english, 1970

34

Nuclear magnetic resonance spectroscopy. Use of carbon-13 isotropic shifts as a probe of mechanisms of spin transmission in metal complexes. Some pyridine-type bases and triphenylphosphine complexed to nickel(II) and cobalt(II) acetylacetonates

Roberts, John D., Doddrell, David.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 715 KB

english, 1970

35

Kinetic studies of exchange between metallic mercury and mercury compounds in solution. III

Pollard, Derek R., Marshall, R. A. G.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 718 KB

english, 1970

36

Electron spin resonance study of the anion radicals of 1-nitro-2,4,6-triphenylbenzene

Jones, Marvin Thomas., Feighan, M. Josita.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 891 KB

english, 1970

37

Detection of the free durosemiquinone anion by electron nuclear double resonance induced electron spin resonance

Allendoerfer, Robert D., Papez, Richard J.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 212 KB

english, 1970

38

Formation of Wurster's blue in benzene at 25.deg.

Steigman, Joseph., Cronkright, Walter.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 877 KB

english, 1970

39

Nybomycin. IV. Total synthesis of deoxynybomycin

Rinehart, Kenneth L., Forbis, Richard M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 263 KB

english, 1970

40

Silver(I) ion catalyzed rearrangements of strained .sigma. bonds. IV. Fate of tricyclo[4.1.0.02,7]heptane

Paquette, Leo A., Allen, George Rodger., Henzel, Richard P.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 248 KB

english, 1970

41

Mechanism of photoisomerization in a 1,3-diazabicyclo[3.1.0]hex-3-ene

Thap Do Minh, ., Trozzolo, Anthony M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 359 KB

english, 1970

42

Applications of artificial intelligence for chemical inference. IV. Saturated amines diagnosed by their low resolution mass spectra and nuclear magnetic resonance spectra

Djerassi, Carl., Buchs, Armand., Duffield, Alan M., Schroll, Gustav., Delfino, Allan B., Buchanan, Bruce G., Sutherland, Georgia L., Feigenbaum, Edward A., Lederberg, Joshua.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 927 KB

english, 1970

43

Borohydride reduction of .sigma.-bonded organopalladium complexes in the norbornenyl-nortricyclenyl system. Evidence against a radical mechanism

Vedejs, Edwin., Salomon, Mary F.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 313 KB

english, 1970

44

Masthead

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 83 KB

english, 1970

45

Kinetics and stereochemistry of the reaction of diethyl maleate and diethyl fumarate with hydrogen chloride in acetic acid

Fahey, Robert C., Schneider, Hans Joerg.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.00 MB

english, 1970

46

Introduction of the amide function into 1,3,2-dioxaphospholenes with pentavalent phosphorus

Ramirez, Fausto., Bauer, J., Telefus, C. David.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 838 KB

english, 1970

47

Infrared intensities as a quantitative measure of intramolecular interactions. XII. .pi.-Distortions in the ground states of some p-alkylbenzenes

Broxton, Trevor J., Deady, L. W., Katritzky, Alan R., Liu, A., Topsom, R. D.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 649 KB

english, 1970

48

Organosilicon compounds containing monovalent gold

Schmidbaur, Hubert., Shiotani, Akinori.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 275 KB

english, 1970

49

Kinetics of acetolysis of .omega.-tosyloxyalkyltrimethyltins. Evidence for .sigma. participation in cyclopropane formation from 3-toxyloxypropyltrimethyltin

Kuivila, Henry G., Scarpa, Nicholas M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 280 KB

english, 1970

50

Structure of carpesterol

Beisler, John A., Tsay, Yi-Hung., Silverton, J. V., Sato, Y.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 185 KB

english, 1970

51

Stereochemistry of SN1 displacement at a vinylic carbon

Hoffmann, Hans M. R., Kernaghan, George F. P.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 409 KB

english, 1970

52

Electron transfer through organic structural units. VII. Reduction of salicylatopentaamminecobalt(III)

Gould, Edwin S., Liang, Anthony.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 746 KB

english, 1970

53

Stereoselectivity of carbene intermediates. VII. Methylchlorocarbene

Moss, Robert A., Mamantov, Andrew.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 773 KB

english, 1970

54

Facile redistribution of trialkylboranes with trimethylene borate. A simple, general synthesis of alkaneboronic esters and acids from olefins via hydroboration

Brown, Herbert Charles., Gupta, Shyam Kirti.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 268 KB

english, 1970

55

Infrared intensities as a quantitative measure of intramolecular interactions. XIII. Molecular orbital calculations of the intensities of ring-stretching bands of substituted benzenes

Brownlee, R. T. C., Katritzky, Alan R., Sinnott, M. V., Szafran, Miroslaw., Topsom, R. D., Yakhontov, L. N.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 720 KB

english, 1970

56

Excited-state three-ring bond opening in cyclopropyl ketones. Mechanistic organic photochemistry. LX

Zimmerman, Howard E., Flechtner, Thomas W.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 615 KB

english, 1970

57

Diffusion study at 25.deg. with a shearing diffusiometer. Comparison with the Gouy and conductance methods

Dunlop, Peter J., Pepela, C. N., Steel, B. J.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1014 KB

english, 1970

58

Infrared intensities as a quantitative measure of intramolecular interactions. XIV. Groups with donor-acceptor character

Katritzky, Alan R., Keogh, H. J., Ohlenrott, S., Topsom, R. D.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 611 KB

english, 1970

59

d,1-Malabaricanediol. First cyclic natural product derived from squalene in a nonenzymic process

Sharpless, Karl B.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 334 KB

english, 1970

60

Chelation of uranyl ions by adenine nucleotides. IV. Nuclear magnetic resonance investigations, hydrogen-1 and phosphorus-31, of the uranyl-adenosine 5'-diphosphate and uranyl-adenosine 5'-triphosphate systems

Feldman, Isaac., Rich, Kenneth E., Agarwal, Raghunath T.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 924 KB

english, 1970

61

Nature of adsorbed propylene on zinc oxide. I. Formation of .pi.-allyl species

Kokes, Richard J., Dent, A. L.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1.07 MB

english, 1970

62

Electron transfer through organic structural units. VIII. Reductions of pentaamminecobalt(III) complexes in poly(vinylsulfonic acid) solution

Gould, Edwin S.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 508 KB

english, 1970

63

Flow birefringence of persistence length deoxyribonucleic acid. Hydrodynamic properties, optical anisotropy, and hydration shell anisotropy

Harrington, Rodney E.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 1012 KB

english, 1970

64

Molecular photochemistry. XXV. Quenching of the fluorescence of norcamphor and its derivatives by trans-1,2-dicyanoethylene and cis-1,2-diethoxyethylene. Evidence for two distinct quenching mechanisms

Turro, Nicholas J., Dalton, J. Christopher., Farrington, Mark., Pond, David M.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 266 KB

english, 1970

65

Nature of adsorbed propylene on zinc oxide. II. Reactions of .pi.-allyl species

Kokes, Richard J., Dent, A. L.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 695 KB

english, 1970

66

Photochemistry of di-tert-butyl ketone and structural effects on the rate and efficiency of intersystem crossing of aliphatic ketones

Yang, Nien-Chu., Feit, Eugene D., Hui, Man Him., Turro, Nicholas J., Dalton, J. Christopher.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 399 KB

english, 1970

67

Photochemical transformations. XLXI. 2-Thiobenzpropiolactone

Chapman, Orville L., McIntosh, Colin L.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 215 KB

english, 1970

68

Reaction of the active site of papain with a reporter group labeled phenacyl halide

Kaiser, Emil T., Furlanetto, Richard W.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 375 KB

english, 1970

69

Proton transfer reactions of nickel(II)-triglycine

Margerum, Dale W., Billo, E. J.

Journal:

Journal of the American Chemical Society

Year:

1970

Language:

english

File:

PDF, 888 KB

english, 1970