Volume 95; Issue 7

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Journal of the American Chemical Society
Volume 95; Issue 7

Journal of the American Chemical Society

Volume 95; Issue 7

1

Crystal structure and location of the bridging hydride ligand in .mu.-chloro-.mu.-hydrido-bis[chloro(pentamethylcyclopentadienyl)rhodium(III)], a monogeneous hydrogenation catalyst

Churchill, Melvyn Rowen., Ni, Shirley W. Y.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 740 KB

english, 1973

2

Total synthesis of (+-)-.alpha.- and (+-)-.beta.-copaenes and ylangenes

Corey, E. J., Watt, David S.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.25 MB

english, 1973

3

Differentiation of 1,4- and 1,5-disubstituted imidazoles

Matthews, H. Randall., Rapoport, Henry.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 877 KB

english, 1973

4

Metastable ion characteristics. XXII. Collisional activation spectra of organic ions

McLafferty, F. W., Bente, P. F., Kornfeld, Richard., Tsai, Shih-Chuan., Howe, Ian.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.10 MB

english, 1973

5

Facile reaction of alkyl- and aryldichloroboranes with organic azides. General stereospecific synthesis of secondary amines

Brown, Herbert C., Midland, M. Mark., Levy, Alan B.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 402 KB

english, 1973

6

Synthesis and reactions of anionic phosphide and arsenide complexes derived from disodium tetracarbonylferrate(-II)

Collman, James P., Komoto, R. G., Siegl, W. O.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 264 KB

english, 1973

7

Thermal bond relocation of the syn- and anti-9-tert-butylbicyclo[6.1.0]nona-2,4,6-trienes. Evidence for strict conformational control

Anastassiou, A. G., Griffith, R. C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 385 KB

english, 1973

8

Thermal rearrangement of cis-bicyclo[6.1.0]nona-2,6-dienes

Grimme, Wolfram.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 369 KB

english, 1973

9

Conformational analysis of the sugar ring in nucleosides and nucleotides. Improved method for the interpretation of proton magnetic resonance coupling constants

Altona, C., Sundaralingam, M.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.54 MB

english, 1973

10

Fluxional behavior of undecahydroundecaborate(2-) (B11H112-)

Tolpin, Eugene I., Lipscomb, William N.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 368 KB

english, 1973

11

Ambident behavior of nitrite ion. Reactions of 2,4-dinitrohalobenzenes and 1,2,4-trinitrobenzene with sodium nitrite

Rosenblatt, David H., Dennis, William H., Goodin, Richard D.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 439 KB

english, 1973

12

Concurrent thermolysis and photolysis of basketene. Formation and the interrelation of some new (CH)10 isomers

Allred, Evan L., Beck, Boyd R.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 271 KB

english, 1973

13

Rates of solvolysis of 2-methyl-, 2-tert-butyl-, 2-phenyl-, and 2-cyclopropyl-2-propyl p-nitrobenzoates. Evidence that carbon-13 chemical shifts of carbonium ions do not correlate with the stabilities of solvolytic transition states and the corresponding cationic intermediates

Brown, Herbert C., Peters, Edward N.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 270 KB

english, 1973

14

Electrostatic force theory for a molecule and interacting molecules. III. Overlap effect on the atomic dipole and exchange forces, orbital following and preceding, and the shapes of XmABYn molecules

Nakatsuji, Hiroshi.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.35 MB

english, 1973

15

Anodic oxidations. IX. Anodic oxidation of 2-methoxyethanol

Ross, Sidney D., Barry, John E., Finkelstein, Manuel., Rudd, Eric J.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 775 KB

english, 1973

16

Structure of the peptide antibiotic amphomycin

Bodanszky, Miklos., Sigler, Gerald F., Bodanszky, Agnes.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 784 KB

english, 1973

17

Unequivocal stereochemical assignment by mass spectrometry

MacLeod, J. K., Wells, R. J.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 270 KB

english, 1973

18

3-Iodopropyl radical. Closure to cyclopropane

Drury, Robert F., Kaplan, Leonard.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 632 KB

english, 1973

19

Spectroscopic and structural characterization of ruthenium(II) carbonyl-porphine complexes

Bonnet, J. J., Eaton, S. S., Eaton, G. R., Holm, R. H., Ibers, James A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.10 MB

english, 1973

20

4,9-Methano[11]annulenylidene. Example of a ten-.pi.-electron carbocyclic aromatic carbene

LaBar, Russell A., Jones, W. M.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 396 KB

english, 1973

21

Simulated ab initio molecular orbital technique I. Method

Eilers, James E., Whitman, Donald R.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 836 KB

english, 1973

22

Catalytic action of polyelectrolytes on the alkaline fading reactions of triphenylmethane dyes

Okubo, Tsuneo., Ise, Norio.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 613 KB

english, 1973

23

Electrochemical reduction studies of several bicyclo[6.1.0]nona-2,4,6-trienes and of cis-bicyclo[6.2.0]deca-2,4,6-triene. Search for a polarographic criterion of homoaromaticity

Anderson, Larry B., Broadhurst, Michel J., Paquette, Leo A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 759 KB

english, 1973

24

Absence of significant remote .pi.-bond effects during solvolysis of epimeric annelated 7-cycloheptatrienylmethyl 3,5-dinitrobenzoates

Paquette, Leo A., Thompson, Gerald L.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 331 KB

english, 1973

25

Theoretical analysis of long-range hyperfine interactions in aliphatic free radicals. Orgin of the W and anti-W rules

Ellinger, Y., Rassat, A., Subra, R., Berthier, G.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 281 KB

english, 1973

26

.alpha.-Halo sulfones. XXI. Bishomoconjugative rearrangement pathway. Structural bond relocation attending the dehydrohalogenation of unsaturated cyclic .alpha.-halo ketones and sulfones

Paquette, Leo A., Meisinger, Robert H., Wingard, Robert E.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.48 MB

english, 1973

27

Mass spectroscopy of pyrimidine cyclonucleosides

Lovett, Eva G., Lipkin, David.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 995 KB

english, 1973

28

Biochemical importance of the binding of phosphate by arginyl groups. Model compounds containing methylguanidinium ion

Cotton, F. A., Hazen, E. E., Day, V. W., Larsen, S., Norman, J. G., Wong, S. T. K., Johnson, K. H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 315 KB

english, 1973

29

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 303 KB

english, 1973

30

Structure of the tetracarbonylhydroferrate(1-) ([HFe(CO)4]-) anion

Smith, Michael B., Bau, Robert.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 293 KB

english, 1973

31

Steric courses of chemical reactions. II

Klemperer, W. G.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.66 MB

english, 1973

32

Organometallic chalcogen complexes. XXVI. Synthesis, structure, and bonding of cubane-like tetra-.mu.3-sulfido-tetra-.pi.-pentahaptocyclopentadienyl tetracobalt(III) [Co4(h5-C5H5)4S4] tetramers (n = 0, +1). Stereochemical influence due to oxidation of completely nonbonding tetrahedral metal system

Simon, Gary L., Dahl, Lawrence F.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.36 MB

english, 1973

33

Multiple condensations with methyl .beta.-vinylacrylate

Danishefsky, S., Hatch, W. E., Sax, M., Abola, E., Pletcher, J.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 251 KB

english, 1973

34

Hydrolysis of imidate esters derived from weakly basic amines. II. Influence of general acid-base catalysis on the partitioning of tetrahedral intermediates

Okuyama, Tadashi., Sahn, David J., Schmir, Gaston L.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 886 KB

english, 1973

35

Structures and isomerism of the hydrofluoroborate salts of Reissert compounds

McEwen, William E., Calabro, Michael A., Mineo, Isodore C., Wang, Irene C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 275 KB

english, 1973

36

Accentuation of di-.pi.-methane reactivity by central carbon substitution. Mechanistic and exploratory organic photochemistry. LXXV

Zimmerman, Howard E., Boettcher, Robert J., Braig, Werner.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.25 MB

english, 1973

37

Olefin isomerizations accompanying the hydroformylation of 3-methyl-1-hexene-3-d1

Casey, Charles P., Cyr, Clifford R.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 782 KB

english, 1973

38

Cyclization of mono- and dimethylated dihalides to five- and six-membered ring halonium ions

Peterson, Paul E., Bonazza, Benedict R., Henrichs, Paul Mark.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 924 KB

english, 1973

39

Ion cyclotron resonance spectroscopy. Neighboring group effects in the gas-phase ionization of .beta.-substituted alcohols

Kim, Jhong K., Findlay, Meredith C., Henderson, W. G., Caserio, Marjorie C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.09 MB

english, 1973

40

Phosphorylation of amides. Evidence for participation in catalysis

Kluger, Ronald., Chan, Joseph L. W.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 334 KB

english, 1973

41

Synthetic spectroscopic models related to coenzymes and base pairs. XI. Solid state ultraviolet irradiation of 1,1'-trimethylenebisthymine and photosensitized irradiation of 1,1'-polymethylenebisthymines

Leonard, Nelson J., McCredie, Robert S., Logue, Marshall W., Cundall, Robert L.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 691 KB

english, 1973

42

Additions to bicyclic olefins. V. Effect of 7,7-dimethyl substituents on the stereochemistry and rates of cyclic additions to norbornenes

Brown, Herbert C., Kawakami, James H., Liu, Kwang-Ting.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1021 KB

english, 1973

43

Stereochemistry of the electrophilic addition of mercuric acetates to cyclopropanes

DePuy, C. H., McGirk, R. H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 212 KB

english, 1973

44

Direct 6-methoxylation of penicillin derivatives. Convenient pathway to substituted .beta.-lactam antibiotics

Baldwin, J. E., Urban, F. J., Cooper, R. D. G., Jose, F. L.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 368 KB

english, 1973

45

Fast intramolecular nucleophilic attack by phenoxide ion on carbamate ester groups

Hutchins, J. E. C., Fife, Thomas H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 610 KB

english, 1973

46

Ab initio calculations on large molecules using molecular fragments. Cumulenes and related molecules

Weimann, Ludwik J., Christoffersen, Ralph E.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.12 MB

english, 1973

47

Generation of a ten-.pi.-electron carbocyclic aromatic carbene by a carbene-carbene rearrangement

Gebert, Paul H., King, Roy W., LaBar, Russell A., Jones, W. M.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 301 KB

english, 1973

48

Amine catalysis of .beta.-ketol dehydration. II. Catalysis via iminium ion formation. General analysis of nucleophilic amine catalysis

Hupe, Donald J., Kendall, Martha C. R., Spencer, Thomas A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 906 KB

english, 1973

49

General method of dehydrogenation using the alkyllithium-N,N,N',N'-tetramethylethylenediamine complex

Harvey, R. G., Nazareno, L., Cho, H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 400 KB

english, 1973

50

Reductive degradation of nitrogen-containing ligands in the presence of cobalt ions

Chatt, J., Elson, C. M., Leigh, G. J.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 276 KB

english, 1973

51

Monoisoprenylated cyclo-L-alanyl-L-tryptophanyl. Biosynthetic precursor of echinulin

Allen, Charles M.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 254 KB

english, 1973

52

Hashish. IX. Synthesis of 7-hydroxy-.DELTA.'-tetrahydrocannabinol (THC). Important active metabolite of .DELTA.'-THC in man

Razdan, Raj K., Uliss, David B., Dalzell, Haldean C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 255 KB

english, 1973

53

Double resonance experiments involving coupled quadrupolar nuclei. I. Boron-boron coupling in 6-methyldecaborane(14)

Sprecher, Richard F., Carter, James C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 255 KB

english, 1973

54

exo-Tricyclo[4.2.1.02,5]nona-3,7-dien-9-yl carbonium ion. New [CH]9+ species from rearrangement of anti-tricyclo[5.2.0.02,5]nona-3,8-dien-6-yl derivatives

Coates, Robert M., Yano, Kazuyuki.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 844 KB

english, 1973

55

Solvolysis of the 2-aryl-2-norbornenyl p-nitrobenzoates. Constant exo:endo rate ratio with increasing electron demand by the 2-aryl group

Peters, Edward N., Brown, Herbert C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 244 KB

english, 1973

56

Photoredox behavior of coordination complexes of nd6 metals. Contrasting redox modes in azidopentacyanocobaltate(III) and azidopentaamminerhodium(III)

Ferraudi, Guillermo., Endicott, John F.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 271 KB

english, 1973

57

Vacuum ultraviolet absorption spectra of the chloromethanes

Russell, B. R., Edwards, L. O., Raymonda, J. W.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 630 KB

english, 1973

58

Iron carbonyl catalyzed isomerization of 3-ethyl-1-pentene. Multiple olefin isomerizations via a .pi.-allyl metal hydride intermediate

Casey, Charles P., Cyr, Clifford R.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 771 KB

english, 1973

59

Activation of homogeneous catalysts by polymer attachment

Grubbs, Robert H., Gibbons, Carl., Kroll, LeRoy C., Bonds, Wesley D., Brubaker, C. H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 384 KB

english, 1973

60

Functionalization of C6(7) of penicillins and cephalosporins. One-step stereoselective synthesis of 7-.alpha.-methoxycephalosporin C

Koppel, G. A., Koehler, R. A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 245 KB

english, 1973

61

Amine catalysis of .beta.-ketol dehydration. I. Catalysis by aqueous solutions of tertiary amines

Hupe, Donald J., Kendall, Martha C. R., Sinner, Gregory T., Spencer, Thomas A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.13 MB

english, 1973

62

Mechanism of the thermolysis of benzoyloxymethyl phenyl sulfoxide. New sulfoxide fragmentation reaction

Maricich, Tom J., Jourdenais, Richard A., Harrington, Clinton K.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 254 KB

english, 1973

63

Reaction of representative olefins with dichloroborane ethyl etherate induced by boron trichloride. Exceptionally simple, general synthesis of alkyldichloroboranes and alkylboronic acid derivatives via hydroboration

Brown, Herbert C., Ravindran, N.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 289 KB

english, 1973

64

2,3,7,8-Tetramethoxythianthrene dication. Isolable thianthrene dication

Glass, Richard S., Britt, William J., Miller, William N., Wilson, George S.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 293 KB

english, 1973

65

Electronic structure of silane hydride anion (SiH5-) and model studies of inter- and intramolecular exchange in pentacoordinate silicon species. Ab initio investigation

Wilhite, Douglas L., Spialter, Leonard.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 464 KB

english, 1973

66

Relative reactivities of ammonia and amide ion in addition to 4-chlorobenzyne

Bunnett, J. F., Kim, Jhong Kook.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 709 KB

english, 1973

67

Catalysis in ester cleavage. IV. One-proton solvation bridge intramolecular carboxylate catalysis of ester hydrolysis

Minor, Stephen S., Schowen, Richard L.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 356 KB

english, 1973

68

Solvolysis of 1-aryl-1-cyclopropyl-1-ethyl p-nitrobenzoates. Evidence for major increases in electron supply by the cyclopropyl group with increasing electron demand at the cationic center

Peters, Edward N., Brown, Herbert C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 269 KB

english, 1973

69

Photochemistry of 4-tert-butyl-2,6-dimethylpyrylium perchlorate. Evidence for an oxoniabenzvalene intermediate

Barltrop, J. A., Dawes, K., Day, A. C., Summers, A. J. H.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 361 KB

english, 1973

70

Photolysis of 4-substituted 1,2,3-benzotriazine 3-N-oxides

Horspool, W. M., Kershaw, J. R., Murray, A. W., Stevenson, G. M.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 258 KB

english, 1973

71

Molecular properties of the triatomic difluorides beryllium difluoride, boron difluoride, difluoromethylene, nitrogen difluoride and oxygen difluoride

Rothenberg, Stephen., Schaefer, Henry F.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 723 KB

english, 1973

72

Charge transfer complexes of purines and pyrimidines. 9-Cyclohexyladenine-iodine in organic solvents and in the solid state

Van der Helm, Dick., Christian, Sherril D., Lin, Lung-Nan.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 271 KB

english, 1973

73

Resonance energies of aromatic hydrocarbons. Quantitative test of resonance theory

Herndon, William C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 339 KB

english, 1973

74

Free-radical chemistry of organophosphorus compounds. III. .alpha. vs. .beta. Scission in reactions of alkoxy and thiyl radicals with trivalent organophosphorus derivatives

Bentrude, Wesley G., Hansen, Eric R., Khan, Wajid A., Min, Tae B., Rogers, Peter E.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 991 KB

english, 1973

75

Photochemical synthesis. 52. Thione photochemistry. II. Preparation of an .alpha.-dithione and the .alpha.-dithione-1,2-dithiete equilibrium

Kuesters, W., De Mayo, P.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 265 KB

english, 1973

76

Organometallic pnicogen complexes. VII. Synthesis, structure and bonding of the cubane-like metal cluster tetra-.mu.3-phosphido-tetra-.pi.-pentahaptocyclopentadienyl tetracobalt(III) [Co4(h5-C5H5)4P4]. First reported organometallic complex containing a naked phosphorus atom as a ligand

Simon, Gary L., Dahl, Lawrence F.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.12 MB

english, 1973

77

Masthead

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 95 KB

english, 1973

78

Crystal and molecular structure of 1,1'-trimethylenebisthymine (Thy-C3-Thy). Environment of a solid state photochemical reaction

Frank, JoAnn K., Paul, Iain C.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1012 KB

english, 1973

79

Sensitized photoaquation of thiocyanatopentaamminechromium(III) and chloropentaamminechromium(III) ions by excited singlet riboflavine

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 640 KB

english, 1973