Volume 98; Issue 2

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Journal of the American Chemical Society
Volume 98; Issue 2

Journal of the American Chemical Society

Volume 98; Issue 2

1

The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities

Kamlet, Mortimer J., Taft, R. W.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 736 KB

english, 1976

2

Nitrosoarene complexes of ruthenium. Nitrosation of activated aromatic compounds by the coordinated nitrosyl group

Bowden, William L., Little, William F., Meyer, Thomas J.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 577 KB

english, 1976

3

On the stereochemistry of polar 2 + 2 cycloadditions

Epiotis, N. D., Yates, R. L., Carlberg, D., Bernardi, F.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 962 KB

english, 1976

4

Overlap repulsion as an important contributor to aromaticity

Epiotis, Nicolaos D., Yates, Ronald L.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 940 KB

english, 1976

5

Synthesis of (+-)-crotepoxide, (+-)-epicrotepoxide, and (+-)-isocrotepoxide

Demuth, Martin R., Garrett, Patricia E., White, James D.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 266 KB

english, 1976

6

Quantitative proton affinities, ionization potentials, and hydrogen affinities of alkylamines

Aue, Donald H., Webb, Hugh M., Bowers, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 846 KB

english, 1976

7

The stereochemical consequences of electron delocalization in extended .pi. systems. An interpretation of the cis effect exhibited by 1,2-disubstituted ethylenes and related phenomena

Bingham, Richard C.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 803 KB

english, 1976

8

The electronic origin of geometrical deformations in cyclohexadienyl and cyclobutenyl transition metal complexes

Hoffmann, Roald, Hofmann, Peter

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 819 KB

english, 1976

9

Magnetic circular dichroism studies of myoglobin complexes. Correlations with heme spin state and axial ligation

Vickery, Larry, Nozawa, Tsunenori, Sauer, Kenneth

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 861 KB

english, 1976

10

Selectivity in the olefin metathesis of unsymmetrically substituted ethylenes

McGinnis, James, Katz, Thomas J., Hurwitz, Samuel

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 247 KB

english, 1976

11

A thermodynamic analysis of solvation effects on the basicities of alkylamines. An electrostatic analysis of substituent effects

Aue, Donald H., Webb, Hugh M., Bowers, Michael T.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.54 MB

english, 1976

12

Ab initio SCF computations on benzene and the benzenium ion using a large contracted gaussian basis set

Ermler, Walter C., Mulliken, Robert S., Clementi, Enrico

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 806 KB

english, 1976

13

Theory and application of photoelectron spectroscopy. 60. Phospholes. Electronic structure

Schaefer, Werner, Schweig, Armin, Mathey, Francois

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 757 KB

english, 1976

14

Asymmetric synthesis of R and S .alpha.-alkylalkanoic acids from metalation and alkylation of chiral 2-oxazolines

Meyers, A. I., Knaus, Gerald, Kamata, Kazuyuki, Ford, Michael E.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.14 MB

english, 1976

15

Directive effects in the electrophilic substitution of deltahedral boranes and heteroboranes. Halogenation of 1-thiadecaborane(9). Unusually long boron-11 spin-lattice relaxation times

Smith, Wayne L., Meneghelli, B. J., McClure, Natalie, Rudolph, R. W.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 419 KB

english, 1976

16

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 130 KB

english, 1976

17

Proton magnetic resonance studies of the effects of sugar hydroxyl dissociation on nucleoside conformation. Arabinosyl nucleosides with an intramolecular hydrogen bond between the pentose O(5') and O(2')

Remin, M., Darzynkiewicz, E., Dworak, A., Shugar, D.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.04 MB

english, 1976

18

Determination of positional weighting factors for the Swain and Lupton substituent constants f and r

Williams, S. G., Norrington, F. E.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.02 MB

english, 1976

19

Derivatives of the hypho class of boron hydrides. I. The molecular structure and nuclear magnetic resonance spectra of stereochemically nonrigid bis(trimethylphosphine)hexaborane(10)

Mangion, Margaret, Hertz, R. K., Denniston, M. L., Long, J. R., Clayton, W. R., Shore, S. G.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 621 KB

english, 1976

20

Negatively substituted trimethylenecyclopropanes and their radical anions

Fukunaga, Tadamichi, Gordon, Michael D., Krusic, Paul J.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 373 KB

english, 1976

21

Carbon-13 nuclear magnetic resonance spectroscopy, a probe to dynamic solvation. Anisotropic and internal motion in aminobiphenyls and their salts

Levy, George C., Holak, Tadeusz, Steigel, Alois

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 533 KB

english, 1976

22

Magnetic circular dichroism studies of low-spin cytochromes. Temperature dependence and effects of axial coordination on the spectra of cytochrome c and cytochrome b5

Vickery, Larry, Nozawa, Tsunenori, Sauer, Kenneth

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 789 KB

english, 1976

23

Cyclopentadienylnitrosylthiocarbonylmanganese dimer. A novel complex believed to contain carbon-bridging thiocarbonyl groups

Efraty, Avi, Arneri, Ruza, Huang, M. H. A.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 305 KB

english, 1976

24

Thyroid hormone stereochemistry. IV. Molecular conformation of 3'-isopropyl-3,5-diiodo-L-thyronine in the crystal and in solution

Fawcett, J. Keith, Camerman, Norman, Camerman, Arthur

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 495 KB

english, 1976

25

The temperature dependence of carbon-13 nuclear magnetic resonance shifts. Limiting factors and stereochemical applications

Schneider, Hans Joerg, Freitag, Wolfgang

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 466 KB

english, 1976

26

Additions and Corrections - Matrix Photolysis of 1,2,3-Thiadiazole. On the Possible Involvement of Thiirene

Krantz, A., Laureni, J.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

27

Analysis of the reactivity of alkenylidenecyclopropanes in cycloaddition reactions

Pasto, Daniel J., Borchardt, John K., Fehlner, Thomas P., Baney, Harry F., Schwartz, Maurice E.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 437 KB

english, 1976

28

Cobalt-59 nuclear quadrupole resonance spectra and low temperature carbon-13 magnetic resonance spectra of X3SnCo(CO)4 compounds

Lichtenberger, Dennis L., Kidd, Dennis R., Loeffler, Paul A., Brown, Theodore L.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 286 KB

english, 1976

29

Photolysis of silyl azides. Generation and reactions of silicon-nitrogen (p.pi.-p.pi.) doubly bonded intermediates. [R2Si:NR]

Parker, D. R., Sommer, L. H.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 338 KB

english, 1976

30

Photosensitized oxygenation of Nb-methoxycarbonyltryptophan methyl ester and Nb-methoxycarbonyltryptamine. Isolation and novel transformations of a 3a-hydroxyperoxypyrroloindole

Nakagawa, Masako, Okajima, Haruo, Hino, Tohru

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 375 KB

english, 1976

31

Characterization and molecular structure of 1-hydro-2,8,9-trioxa-1-phospha-5-aza-tricyclo[3.3.3.0]undecane tetrafluoroborate. Pentacoordination of phosphorus

Clardy, J. C., Milbrath, D. S., Springer, J. P., Verkade, J. G.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 279 KB

english, 1976

32

Observed and calculated Faraday B terms in monosubstituted benzenes

Kaito, Akira, Tajiri, Akio, Hatano, Masahiro

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 492 KB

english, 1976

33

Masthead

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 116 KB

english, 1976

34

New synthetic reactions. Catalytic vs. stoichiometric allylic alkylation. Stereocontrolled approach to steroid side chain

Trost, Barry M., Verhoeven, Thomas R.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 383 KB

english, 1976

35

Additions and Corrections - Estimation of Solvolysis Rates of Cyclic Secondary Substrates

Harris, Milton, McManus, Samuel

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

36

A molecular orbital interpretation of the static, dynamic, and chemical properties of CH2X radicals

Bernardi, Fernando, Epiotis, Nicolaos D., Cherry, William, Schlegel, H. Bernhard, Whangbo, Myung-Hwan, Wolfe, Saul

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.14 MB

english, 1976

37

Mechanisms of ligand association in complexes of the type RML3+X- (M = nickel, palladium, platinum). I. Mechanistic aspects of nuclear magnetic resonance line shape analysis for intermolecular exchange in non-first-order multispin systems

Meakin, P., English, A. D., Jesson, J. P.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 846 KB

english, 1976

38

A reinterpretation of paramagnetic line broadening in the nuclear magnetic resonance spectra of amino acids and peptides. I. The copper(II)-glycine system

Beattie, James K., Fensom, Donald J., Freeman, Hans C.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 929 KB

english, 1976

39

Resonance Raman study of the thermochromic phase transition of a polydiacetylene

Exarhos, Gregory J., Risen, William M., Baughman, Ray H.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 744 KB

english, 1976

40

Elimination reactions induced by photoenolization of o-alkylbenzophenones

Tseng, Shin-Shyong, Ullman, Edwin F.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 514 KB

english, 1976

41

Reactions of (CO)5WC(Tol)2 with alkenes. A Model for structural selectivity in the olefin metathesis reaction

Casey, Charles P., Tuinstra, Hendrik E., Saeman, Marian C.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 218 KB

english, 1976

42

Additions and Corrections - Irreversible Inhibition of Δ 5 -3-Ketosteroid Isomerase by 5,10-Secosteroids

Batzold, F., Robinson, C.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

43

MO calculations on metal carbene complexes and metal acyl complexes. The importance of the LUMO in determining the site of nucleophilic attack

Block, Toby F., Fenske, Richard F., Casey, Charles P.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 350 KB

english, 1976

44

Fast thermal Z,E isomerization in symmetrical overcrowded ethylenes. Low barriers due to ground-state destabilization

Agranat, Israel, Tapuhi, Yitzhak

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 278 KB

english, 1976

45

A model for the triplet state photochemical isomerization of azomethine dyes

Herkstroeter, William G.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 820 KB

english, 1976

46

On the question of paramagnetic "ring currents" in pyracylene and related molecules

Coulson, C. A., Mallion, R. B.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.00 MB

english, 1976

47

The reduction of molybdenum(II) trifluoroacetate by pulse radiolysis in methanol

Baxendale, J. H., Garner, C. David, Senior, Roger G., Sharpe, Peter

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 287 KB

english, 1976

48

Additions and Cotrrections - Phase Transfer Catalysis. An Evaluation of Catalysts.

Herriott, Arthur, Picker, Donald

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

49

Electronic structure of dicarbonyls. Glyoxal excited states

Dykstra, Clifford E., Schaefer, Henry F.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.43 MB

english, 1976

50

Trivalent copper as a probable intermediate in the reaction catalyzed by galactose oxidase

Dyrkacz, Gary R., Libby, R. Daniel, Hamilton, Gordon A.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 430 KB

english, 1976

51

Stable carbocations. 184. 2,4-Dehydro-5-homoadamantyl cations

Olah, George A., Liang, Gao, Babiak, Kevin A., Morgan, Thomas K., Murray, Roger K.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 468 KB

english, 1976

52

Pentacarbonyliron(0) photocatalyzed hydrogenation and isomerization of olefins

Schroeder, Mark A., Wrighton, Mark S.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1005 KB

english, 1976

53

Additions and Corrections - Stable Carbocations. CLXXXII. The Acetoacetylium and Diacetoacetylium Ions.

Olah, G., Germain, Alain, Lin, Henry, Dunne, Kenneth

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 130 KB

english, 1976

54

The effect of temperature and solvent environment on the conformational stability of 11-cis-retinal

Birge, Robert R., Sullivan, Michael J., Kohler, Bryan E.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.22 MB

english, 1976

55

Mechanisms of ligand association in complexes of the type RML3+X- (M = nickel, palladium, platinum). II. The mechanisms of the reactions HML3+ + L .dha. HML4+ (L = triethylphosphine)

English, A. D., Meakin, P., Jesson, J. P.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.43 MB

english, 1976

56

Additions and Corrections - Remote Anodic Substitution of Ketones

Becker, James, Byrd, Larry, Miller, Larry, So, Ying-Hung

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

57

Additions and Corrections - Enantioselective Oxirane Synthesis by Means of Dimethylsulfonium Metylide and Chiral Phase-Transfer Catalysts

Hiyama, Tamejiro, Mishima, Takashi, Sawada, Hiroyuki, Nozaki, Hitosi

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

58

Negatively substituted trimethylenecyclopropane dianions

Fukunaga, Tadamichi

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 245 KB

english, 1976

59

An ab initio calculation of the bonding, excited states, and g value of tetrachlorocobaltate(II), (CoCl4)2-

Hillier, Ian H., Kendrick, John, Mabbs, Frank E., Garner, C. David

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 368 KB

english, 1976

60

Kinetic and equilibrium chlorine isotope effects in the cyclization of 2-chloroethanol in protic solvents

Cromartie, Thomas H., Swain, C. Gardner

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 784 KB

english, 1976

61

On the orbital interactions of three-membered rings with .pi. systems. Electronic structure of alkenylidenecyclopropanes

Pasto, Daniel J., Fehlner, Thomas P., Schwartz, Maurice E., Baney, Harry F.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 496 KB

english, 1976

62

Synthetic models of deoxyribonucleic acid complexes with antimalarial compounds. I. Interaction of aminoquinoline with adenine and thymine

Bolte, J., Demuynck, C., Lhomme, J.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 367 KB

english, 1976

63

Kinetic applications of electron paramagnetic resonance spectroscopy. XXII. Dialkylaminothiyl radicals

Maillard, B., Ingold, K. U.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 502 KB

english, 1976

64

Complexation of carbonyl oxide zwitterions

Bailey, Philip S., Rustaiyan, A., Ferrell, T. M.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 301 KB

english, 1976

65

The nitrogen-15 nuclear magnetic resonance of friend leukemic cell [Gly-15N] hemoglobin. The resolution of noncovalent bonding interactions

Lapidot, A., Irving, C. S., Malik, Z.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 380 KB

english, 1976

66

Kinetic applications of electron paramagnetic resonance spectroscopy. XXIII. Cyanomethyl radicals

Kaba, R. A., Ingold, K. U.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 494 KB

english, 1976

67

Site of nucleophilic attack on acylpentacarbonylmanganese(I) compounds

Casey, Charles P., Bunnell, Charles A.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 743 KB

english, 1976

68

Benzo[1,2:3,4]dicyclobutene

Thummel, Randolph P.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 277 KB

english, 1976

69

Thermodynamics of exciplex formation by time-resolved nanosecond flash spectroscopy

Creed, David, Wine, Paul H., Caldwell, Richard A., Melton, Lynn A.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 373 KB

english, 1976

70

Nitrogen-centered free radicals. IX. The ease of formation of thionitroxide radicals

Danen, Wayne C., Newkirk, David D.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 674 KB

english, 1976

71

The photodissociation and high resolution laser photodissociation of halogen-substituted toluene cations

Fu, Emil W., Dymerski, Paul P., Dunbar, Robert C.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 696 KB

english, 1976

72

Additions and Corrections - Effect of Crown Ether on the Conformational Equilibrium of Sodium Acetylacetonate

Noe, Eric, Raban, Morton

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976

73

Addtions and Corrections - A Critical Examination of the Applicability of J 13 CH as a Criterion for the Presence of σ Bridging in Cyclopropylcarbinyl Cations

Kelly, David, Brown, Herbert

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 130 KB

english, 1976

74

Electron spin resonance studies of the photolysis of trialkylsilyl peroxides

Cookson, Peter G., Davies, Alwyn G., Fazal, Nasir A., Roberts, Brian P.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 380 KB

english, 1976

75

Crystal and molecular structure of pentaphenoxyphosphorane, (C6H5O)5P. The configuration of acyclic, monocyclic, and spirobicyclic pentaoxyphosphoranes

Sarma, Raghupathy, Ramirez, Fausto, McKeever, Brian, Marecek, James F., Lee, Shuyan

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 895 KB

english, 1976

76

Alkylation of tetracyanoethylene. Reaction with Grignard reagents

Gardner, Hugh C., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 1.03 MB

english, 1976

77

Metathesis of a cyclic trisubstituted alkene. Preparation of polyisoprene from 1-methylcyclobutene

Katz, Thomas J., McGinnis, James, Altus, Craig

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 387 KB

english, 1976

78

Fluorescence of carbonyl compounds. III. Reactivity of n,.pi.* excited states of alkanals

Dalton, J. Christopher, Geiger, Margaret W., Snyder, John J.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 586 KB

english, 1976

79

Laser fluorimetry. Sub-part-per-trillion detection of solutes

Bradley, A. Beatrice, Zare, Richard N.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 264 KB

english, 1976

80

The ionization of feeble organic acids in DMSO-water mixtures. Acidity constants derived by extrapolation to the aqueous state

Cox, Robin A., Stewart, Ross

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 801 KB

english, 1976

81

Additions and Corrections - A General Synthetic Method for Non-K-Region Arene Oxides

Yagi, Haruhiko, Jerina, Donald

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 119 KB

english, 1976